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Problem 4.16 The torsional energy in propane is 14 kJ/mol (3.4 kcal/mol). Because each H,H eclipsing interaction is worth 4.0 kJ/mol (1.0 kcal/mol) of destabilization, how much is one H,CH3 eclipsing interaction worth in destabilization? (See Section 4.10 for an alternate way to arrive at this value.) Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of McGraw-Hill Education. Figure 4.7 Newman projections for Consider one C-C bond only. H CH3 the staggered and eclipsed conformations of propane H propane H • Arbitrarily pick one C to be in front and one C to be in back. • 3 H's on one C • 2 H's and 1 CH3 on the other C CH3 H. H H H H staggered conformation CH3 H Η H H H eclipsed conformation

Problem 4.16 The torsional energy in propane is 14 kJ/mol (3.4 kcal/mol). Because each H,H eclipsing interaction is worth 4.0 kJ/mol (1.0 kcal/mol) of destabilization, how much is one H,CH3 eclipsing interaction worth in destabilization? (See Section 4.10 for an alternate way to arrive at this value.) Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of McGraw-Hill Education. Figure 4.7 Newman projections for Consider one C-C bond only. H CH3 the staggered and eclipsed conformations of propane H propane H • Arbitrarily pick one C to be in front and one C to be in back. • 3 H's on one C • 2 H's and 1 CH3 on the other C CH3 H. H H H H staggered conformation CH3 H Η H H H eclipsed conformation

Organic Chemistry: A Guided Inquiry
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter4: Polar Bonds, Polar Reactions
Section: Chapter Questions
Problem 19E: Are endothermic reactions favorable or unfavorable? ... uphillor downhill?
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Problem 4.16 The torsional energy in propane is 14 kJ/mol (3.4 kcal/mol). Because each H,H eclipsing interaction is worth 4.0 kJ/mol (1.0 kcal/mol) of destabilization, how much is one H,CH3 eclipsing interaction worth in destabilization? (See Section 4.10 for an alternate way to arrive at this value.) Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of McGraw-Hill Education. Figure 4.7 Newman projections for Consider one C-C bond only. H CH3 the staggered and eclipsed conformations of propane H propane H • Arbitrarily pick one C to be in front and one C to be in back. • 3 H's on one C • 2 H's and 1 CH3 on the other C CH3 H. H H H H staggered conformation CH3 H Η H H H eclipsed conformation
Transcribed Image Text:Problem 4.16 The torsional energy in propane is 14 kJ/mol (3.4 kcal/mol). Because each H,H eclipsing interaction is worth 4.0 kJ/mol (1.0 kcal/mol) of destabilization, how much is one H,CH3 eclipsing interaction worth in destabilization? (See Section 4.10 for an alternate way to arrive at this value.) Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of McGraw-Hill Education. Figure 4.7 Newman projections for Consider one C-C bond only. H CH3 the staggered and eclipsed conformations of propane H propane H • Arbitrarily pick one C to be in front and one C to be in back. • 3 H's on one C • 2 H's and 1 CH3 on the other C CH3 H. H H H H staggered conformation CH3 H Η H H H eclipsed conformation
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