Chemistry the Central Science 13th Edition Custom for Lamar University
13th Edition
ISBN: 9781269962667
Author: Theodore L. Brown, H. Eugene LeMay Jr., Bruce E. Bursten, Batherine J. Murphy, Patrick M. Woodward, Matthew W. Stoltzfus
Publisher: Pearson Learning Center
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Chapter 1, Problem 11E
Interpretation Introduction
(a)
Interpretation:
The chemical formula of the compound formed by
Interpretation Introduction
(b)
Interpretation:
The chemical formula of the compound formed by
Interpretation Introduction
(c)
Interpretation:
The chemical formula of the compound formed by
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 1 Solutions
Chemistry the Central Science 13th Edition Custom for Lamar University
Ch. 1.2 - Which of the following is the correct description...Ch. 1.2 - Prob. 1.1.2PECh. 1.5 - Which of the following numbers in your personal...Ch. 1.5 - Practice Exercise 2 The back inside cover of the...Ch. 1.5 - Practice Exercise 1 An object is determined to...Ch. 1.5 - Practice Exercise 2 How many significant figures...Ch. 1.5 - Ellen recently purchased a new hybrid car and...Ch. 1.5 - Practice Exercise 2 It takes 10.5 s for a sprinter...Ch. 1.5 - Prob. 1.5.1PECh. 1.5 - Prob. 1.5.2PE
Ch. 1.6 - Practice Exercise 2 By using a conversion factor...Ch. 1.6 - Practice Exercise 1 Fabiola, who lives in Mexico...Ch. 1.6 - Prob. 1.7.1PECh. 1.6 - Practice Exercise 2 A car travels 28 mi per gallon...Ch. 1.6 - Practice Exercise 2 The surface area of Earth is...Ch. 1.6 - Practice Exercise 1 Composite decking is a...Ch. 1.6 - Prob. 1.9.1PECh. 1.6 - Practice Exercise 2 If the mass of the container...Ch. 1.6 - Practice Exercise 1 Which of the following is the...Ch. 1.6 - Aspirin is composed of 60.0% carbon, 4.5%...Ch. 1.6 - Practice Exercise 1 Which of the following weights...Ch. 1.6 - Practice Exercise 2 How many picometers are there...Ch. 1.6 - Practice Exercise 1 Using Wolfram Alpha...Ch. 1.6 - Practice Exercise 2 Ethylene glycol, the major...Ch. 1.6 - Prob. 1.13.1PECh. 1.6 - Practice Exercise 2 Calculate the density of a...Ch. 1 - The reaction between reactant A (blue spheres) and...Ch. 1 - Prob. 2ECh. 1 - Describe the separation method(s) involved in...Ch. 1 - Prob. 4ECh. 1 - Prob. 5ECh. 1 - Prob. 6ECh. 1 - Prob. 7ECh. 1 - 2447 What are the molecular and empirical formulas...Ch. 1 - When you convert units, how do you decide which...Ch. 1 - Prob. 10ECh. 1 - 2-60 The most common charge associated with...Ch. 1 - Prob. 12ECh. 1 -
2.84 Consider the following organic substances:...Ch. 1 -
2.96 Gallium (Ga) consists of two naturally...Ch. 1 -
2.108 Cyclopropane is an interesting hydrocarbon....Ch. 1 - Write a balanced equation for (a) solid...Ch. 1 - Calculate the molar mass of Ca(NO3)2Ch. 1 - Prob. 18ECh. 1 - Imagine you are working on ways to improve the...Ch. 1 - A key step in balancing chemical equations is...Ch. 1 - a. The characteristic odor of pineapple is due to...Ch. 1 - The complete combustion of octane, Cngs, a...Ch. 1 - Prob. 23ECh. 1 - Prob. 24ECh. 1 -
4.53 Write balanced molecular and net ionic...Ch. 1 - Prob. 26ECh. 1 - Prob. 27ECh. 1 - Prob. 28ECh. 1 -
4.101 Hard water contains Ca2+ , Mg2 + , and Fe2+...Ch. 1 - Prob. 30ECh. 1 - Prob. 31ECh. 1 - Prob. 32ECh. 1 - Imagine that you are climbing a mountain. Is the...Ch. 1 - A gas is confined to a cylinder under constant...Ch. 1 -
5.100 An aluminum can of a soft drink is placed...Ch. 1 - The hydrocarbons acetylene (C2H2) and benzene...Ch. 1 - The precipitation reaction between AgNO3(aq) and...Ch. 1 - Consider the following three moving objects: a...Ch. 1 - The speed of sound in dry air at 20°C is 343 m/s...Ch. 1 - Prob. 40ECh. 1 - Calculate the energy of a photon of...Ch. 1 - Using Heisenberg's uncertainty principle,...Ch. 1 - Prob. 43ECh. 1 - The following do not represent valid ground-state...Ch. 1 - Prob. 45ECh. 1 - Prob. 46ECh. 1 - Arrange the following atoms and ions in order of...Ch. 1 - Prob. 48ECh. 1 - Prob. 49ECh. 1 - The distance from Grand Rapids, Michigan, to...Ch. 1 - Prob. 51ECh. 1 - Prob. 52ECh. 1 - Prob. 53ECh. 1 - Prob. 54ECh. 1 - Prob. 55ECh. 1 - Which of the these molecules has a Lewis structure...Ch. 1 - Prob. 57ECh. 1 - Write the electron configuration for the element...Ch. 1 - (a) Classify each of the following as a pure...Ch. 1 - Prob. 60AECh. 1 - Prob. 61AECh. 1 - Prob. 62AECh. 1 - Prob. 63AECh. 1 - Prob. 64AECh. 1 - Prob. 65AECh. 1 - Prob. 66AECh. 1 - Prob. 67AECh. 1 - Prob. 68AECh. 1 - Ethyl acetate. C4H802, is a fragrant substance...Ch. 1 - Prob. 70AECh. 1 - The iodine bromide molecule, IBr, is an...Ch. 1 - Prob. 72AECh. 1 - Prob. 73AECh. 1 - Prob. 74AECh. 1 - Prob. 75AECh. 1 - Prob. 76AECh. 1 - Prob. 77AECh. 1 -
10.12 The graph below shows the change in...Ch. 1 - Prob. 79AECh. 1 - Prob. 80AECh. 1 - Prob. 81AECh. 1 - Prob. 82AECh. 1 - Prob. 83AECh. 1 - Prob. 84AECh. 1 - Prob. 85AECh. 1 - Prob. 86AECh. 1 - Prob. 87AECh. 1 - Prob. 88AE
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- Hi!! Please provide a solution that is handwritten. Ensure all figures, reaction mechanisms (with arrows and lone pairs please!!), and structures are clearly drawn to illustrate the synthesis of the product as per the standards of a third year organic chemistry course. ****the solution must include all steps, mechanisms, and intermediate structures as required. Please hand-draw the mechanisms and structures to support your explanation. Don’t give me AI-generated diagrams or text-based explanations, no wordy explanations on how to draw the structures I need help with the exact mechanism hand drawn by you!!! I am reposting this—ensure all parts of the question are straightforward and clear or please let another expert handle it thanks!!arrow_forwardHi!! Please provide a solution that is handwritten. Ensure all figures, reaction mechanisms (with arrows and lone pairs please!!), and structures are clearly drawn to illustrate the synthesis of the product as per the standards of a third year organic chemistry course. ****the solution must include all steps, mechanisms, and intermediate structures as required. Please hand-draw the mechanisms and structures to support your explanation. Don’t give me AI-generated diagrams or text-based explanations, no wordy explanations on how to draw the structures I need help with the exact mechanism hand drawn by you!!! I am reposting this—ensure all parts of the question are straightforward and clear or please let another expert handle it thanks!!arrow_forward. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. < cleavage Bond A • CH3 + 26. t cleavage 2°C• +3°C• Bond C Cleavage CH3 ZC '2°C. 26. E Strongest 3°C. 2C. Gund Largest BDE weakest bond In that molecule a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest C bond Produces A Weakest Bond Most Strongest Bond Stable radical Strongest Gund produces least stable radicals b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 人 8°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. methyl radical •CH3 formed in bund A Cleavagearrow_forward
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