Chemistry the Central Science 13th Edition Custom for Lamar University
13th Edition
ISBN: 9781269962667
Author: Theodore L. Brown, H. Eugene LeMay Jr., Bruce E. Bursten, Batherine J. Murphy, Patrick M. Woodward, Matthew W. Stoltzfus
Publisher: Pearson Learning Center
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Textbook Question
Chapter 1, Problem 44E
The following do not represent valid ground-state electron configurations for an atom either because they violate the Pauli exclusion principle or because orbitals are not filled in order of increasing energy. Indicate which of these two principles is violated in each example.
- 1s22s23s1',
- [Xe}6s25d4
- [Ne]3s23d5 .
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(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to
glucose, C6H12O6, and fructose C6H12O6, in acidic solution:
C12H22O11 + H2O → C6H12O6 + C6H12O6
[sucrose]/mol dm³
t/min
0
0.316
14
0.300
39
0.274
60
0.256
80
0.238
110
0.211
(i) Graphically prove the order of the reaction and determine the rate constant of the
reaction.
(ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent
(b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous
solution was examined. The adsorption was modelled using a modified Langmuir
isotherm, yielding the following values of Kat pH = 6.5:
(ii)
T/K
10-10 K
280
2.505
295
1.819
310
1.364
325
1.050
Determine the enthalpy of adsorption, AadsHⓇ.
If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above
conditions, determine Aads Gº.
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Chapter 1 Solutions
Chemistry the Central Science 13th Edition Custom for Lamar University
Ch. 1.2 - Which of the following is the correct description...Ch. 1.2 - Prob. 1.1.2PECh. 1.5 - Which of the following numbers in your personal...Ch. 1.5 - Practice Exercise 2 The back inside cover of the...Ch. 1.5 - Practice Exercise 1 An object is determined to...Ch. 1.5 - Practice Exercise 2 How many significant figures...Ch. 1.5 - Ellen recently purchased a new hybrid car and...Ch. 1.5 - Practice Exercise 2 It takes 10.5 s for a sprinter...Ch. 1.5 - Prob. 1.5.1PECh. 1.5 - Prob. 1.5.2PE
Ch. 1.6 - Practice Exercise 2 By using a conversion factor...Ch. 1.6 - Practice Exercise 1 Fabiola, who lives in Mexico...Ch. 1.6 - Prob. 1.7.1PECh. 1.6 - Practice Exercise 2 A car travels 28 mi per gallon...Ch. 1.6 - Practice Exercise 2 The surface area of Earth is...Ch. 1.6 - Practice Exercise 1 Composite decking is a...Ch. 1.6 - Prob. 1.9.1PECh. 1.6 - Practice Exercise 2 If the mass of the container...Ch. 1.6 - Practice Exercise 1 Which of the following is the...Ch. 1.6 - Aspirin is composed of 60.0% carbon, 4.5%...Ch. 1.6 - Practice Exercise 1 Which of the following weights...Ch. 1.6 - Practice Exercise 2 How many picometers are there...Ch. 1.6 - Practice Exercise 1 Using Wolfram Alpha...Ch. 1.6 - Practice Exercise 2 Ethylene glycol, the major...Ch. 1.6 - Prob. 1.13.1PECh. 1.6 - Practice Exercise 2 Calculate the density of a...Ch. 1 - The reaction between reactant A (blue spheres) and...Ch. 1 - Prob. 2ECh. 1 - Describe the separation method(s) involved in...Ch. 1 - Prob. 4ECh. 1 - Prob. 5ECh. 1 - Prob. 6ECh. 1 - Prob. 7ECh. 1 - 2447 What are the molecular and empirical formulas...Ch. 1 - When you convert units, how do you decide which...Ch. 1 - Prob. 10ECh. 1 - 2-60 The most common charge associated with...Ch. 1 - Prob. 12ECh. 1 -
2.84 Consider the following organic substances:...Ch. 1 -
2.96 Gallium (Ga) consists of two naturally...Ch. 1 -
2.108 Cyclopropane is an interesting hydrocarbon....Ch. 1 - Write a balanced equation for (a) solid...Ch. 1 - Calculate the molar mass of Ca(NO3)2Ch. 1 - Prob. 18ECh. 1 - Imagine you are working on ways to improve the...Ch. 1 - A key step in balancing chemical equations is...Ch. 1 - a. The characteristic odor of pineapple is due to...Ch. 1 - The complete combustion of octane, Cngs, a...Ch. 1 - Prob. 23ECh. 1 - Prob. 24ECh. 1 -
4.53 Write balanced molecular and net ionic...Ch. 1 - Prob. 26ECh. 1 - Prob. 27ECh. 1 - Prob. 28ECh. 1 -
4.101 Hard water contains Ca2+ , Mg2 + , and Fe2+...Ch. 1 - Prob. 30ECh. 1 - Prob. 31ECh. 1 - Prob. 32ECh. 1 - Imagine that you are climbing a mountain. Is the...Ch. 1 - A gas is confined to a cylinder under constant...Ch. 1 -
5.100 An aluminum can of a soft drink is placed...Ch. 1 - The hydrocarbons acetylene (C2H2) and benzene...Ch. 1 - The precipitation reaction between AgNO3(aq) and...Ch. 1 - Consider the following three moving objects: a...Ch. 1 - The speed of sound in dry air at 20°C is 343 m/s...Ch. 1 - Prob. 40ECh. 1 - Calculate the energy of a photon of...Ch. 1 - Using Heisenberg's uncertainty principle,...Ch. 1 - Prob. 43ECh. 1 - The following do not represent valid ground-state...Ch. 1 - Prob. 45ECh. 1 - Prob. 46ECh. 1 - Arrange the following atoms and ions in order of...Ch. 1 - Prob. 48ECh. 1 - Prob. 49ECh. 1 - The distance from Grand Rapids, Michigan, to...Ch. 1 - Prob. 51ECh. 1 - Prob. 52ECh. 1 - Prob. 53ECh. 1 - Prob. 54ECh. 1 - Prob. 55ECh. 1 - Which of the these molecules has a Lewis structure...Ch. 1 - Prob. 57ECh. 1 - Write the electron configuration for the element...Ch. 1 - (a) Classify each of the following as a pure...Ch. 1 - Prob. 60AECh. 1 - Prob. 61AECh. 1 - Prob. 62AECh. 1 - Prob. 63AECh. 1 - Prob. 64AECh. 1 - Prob. 65AECh. 1 - Prob. 66AECh. 1 - Prob. 67AECh. 1 - Prob. 68AECh. 1 - Ethyl acetate. C4H802, is a fragrant substance...Ch. 1 - Prob. 70AECh. 1 - The iodine bromide molecule, IBr, is an...Ch. 1 - Prob. 72AECh. 1 - Prob. 73AECh. 1 - Prob. 74AECh. 1 - Prob. 75AECh. 1 - Prob. 76AECh. 1 - Prob. 77AECh. 1 -
10.12 The graph below shows the change in...Ch. 1 - Prob. 79AECh. 1 - Prob. 80AECh. 1 - Prob. 81AECh. 1 - Prob. 82AECh. 1 - Prob. 83AECh. 1 - Prob. 84AECh. 1 - Prob. 85AECh. 1 - Prob. 86AECh. 1 - Prob. 87AECh. 1 - Prob. 88AE
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