Bundle: Physical Chemistry, 2nd + Student Solutions Manual
2nd Edition
ISBN: 9781285257594
Author: David W. Ball
Publisher: Cengage Learning
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Chapter 1, Problem 1.15E
A 2.0 L soda bottle is pressurized with 4.5 atm of CO2 at 298 K. If the temperature is increased to 317 K, what is the pressure of the CO2?
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
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ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
in the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstant
Chapter 1 Solutions
Bundle: Physical Chemistry, 2nd + Student Solutions Manual
Ch. 1 - A bomb calorimeter is a study metal vessel in...Ch. 1 - Difference between the system and the...Ch. 1 - Prob. 1.3ECh. 1 - Prob. 1.4ECh. 1 - Prob. 1.5ECh. 1 - Prob. 1.6ECh. 1 - Prob. 1.7ECh. 1 - A pot of cold water is heated on a stove, and when...Ch. 1 - hat difference is necessary for heat to flow...Ch. 1 - What is the value of FT for a sample of gas whose...
Ch. 1 - What is the value of FP for a sample of gas whose...Ch. 1 - Prob. 1.12ECh. 1 - Hydrogen gas is used in weather balloon because it...Ch. 1 - Prob. 1.14ECh. 1 - A 2.0 L soda bottle is pressurized with 4.5 atm of...Ch. 1 - The Mount Pinatubo volcano eruption in 1991...Ch. 1 - Prob. 1.17ECh. 1 - Scottish physicist W. J. M. Rankine proposed an...Ch. 1 - Use the two appropriate values of R to determine a...Ch. 1 - Prob. 1.20ECh. 1 - Pressures of gases in mixtures are referred to as...Ch. 1 - Earths atmosphere is approximately 80 N2 and 20...Ch. 1 - The atmospheric surface pressure on Venus is 90...Ch. 1 - Prob. 1.24ECh. 1 - Prob. 1.25ECh. 1 - In the anaerobic oxidation of glucose by yeast,...Ch. 1 - What are the slopes of the following lines at the...Ch. 1 - For the following function, evaluate the...Ch. 1 - Determine the expressions for the following,...Ch. 1 - Determine the expressions for the following,...Ch. 1 - Prob. 1.31ECh. 1 - Prob. 1.32ECh. 1 - Prob. 1.33ECh. 1 - Prob. 1.34ECh. 1 - What properties of a nonideal gas do the Vander...Ch. 1 - Prob. 1.36ECh. 1 - Prob. 1.37ECh. 1 - Calculate the Boyle temperatures for carbon...Ch. 1 - Prob. 1.39ECh. 1 - Prob. 1.40ECh. 1 - Table 1.4 show that the second virial coefficient...Ch. 1 - Prob. 1.42ECh. 1 - What is the van der Waals constant a for Ne in...Ch. 1 - Prob. 1.44ECh. 1 - Under what conditions would the van der Waals...Ch. 1 - By definition, the compressibility of an ideal gas...Ch. 1 - The second virial coefficient B and the third...Ch. 1 - Use the approximation 1 x-1 1 x x2 to...Ch. 1 - Why is nitrogen a good choice for the study of...Ch. 1 - Evaluate for a gas following the Redlich-Kwong...Ch. 1 - Numerically evaluate for one mole of methane...Ch. 1 - Under what conditions of volume does a van der...Ch. 1 - At high temperatures, one of the van der Waals...Ch. 1 - Under what conditions of temperature does a...Ch. 1 - The Berthelot equation of state for one mole of...Ch. 1 - Prob. 1.56ECh. 1 - Referring to exercises 1.6 and 1.7, does it matter...Ch. 1 - Prob. 1.58ECh. 1 - Use Figure 1.11 to construct the cyclic rule...Ch. 1 - Prob. 1.60ECh. 1 - Prob. 1.61ECh. 1 - Calculate for one mole of an ideal gas at STP and...Ch. 1 - Prob. 1.63ECh. 1 - Show that = T/p for an ideal gas.Ch. 1 - Determine an expression for V/T p, n in terms of ...Ch. 1 - Prob. 1.66ECh. 1 - Prob. 1.67ECh. 1 - Perform a units analysis on the exponent of the...Ch. 1 - Using the barometric formula, calculate the...Ch. 1 - The barometric formula can also be used for...Ch. 1 - Prob. 1.71ECh. 1 - Prob. 1.72ECh. 1 - Prob. 1.73ECh. 1 - Prob. 1.74ECh. 1 - Prob. 1.75ECh. 1 - Prob. 1.76ECh. 1 - Prob. 1.77ECh. 1 - Prob. 1.78ECh. 1 - Prob. 1.79ECh. 1 - Use the ideal gas law to symbolically prove the...Ch. 1 - Prob. 1.81E
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- true or false, given that a 20.00 mL sample of NaOH took 24.15 mL of 0.141 M HCI to reach the endpoint in a titration, the concentration of the NaOH is 1.17 M.arrow_forwardin the bromothymol blue experiment, pKa was measured. A closely related compound has a Ka of 2.10 x 10-5. What is the pKa?a) 7.1b) 4.7c) 2.0arrow_forwardcalculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forward
- true or falsegiven these two equilibria with their equilibrium constants:H2(g) + CI2(l) ↔ 2HCI(g) K= 0.006 CI2(l) ↔ CI2(g) K= 0.30The equilibrium contstant for the following reaction is 1.8H2(g) + CI2 ↔ 2HCI(g)arrow_forwardI2(g) + CI2(g) ↔ 2ICIK for this reaction is 81.9. Find the equilibrium concentration of I2 if the inital concentration of I2 and CI2 are 0.010 Marrow_forwardtrue or false,the equilibrium constant for this reaction is 0.50.PCI5(g) ↔ PCI3(g) + CI2(g)Based on the above, the equilibrium constant for the following reaction is 0.25.2PCI5(g) ↔. 2PCI3(g) + 2CI2(g)arrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY