why are these sterically hindered what does it even mean to be stericaly hindered

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
why are these sterically hindered what does it even mean to be stericaly hindered
Steric Hindrance Favors the Elimination Product
However, if either the primary alkyl halide or the nucleophile/base is sterically hindered, then the
nucleophile will have difficulty getting to the back side of the a-carbon but will be able to remove
the more accessible proton. As a result, elimination will win the competition.
the primary alkyl halide is sterically hindered
Br + CH3O
the nucleophile is sterically hindered
Br +
Xó
40%
15%
+
60%
85%
CH3OH + Br
Хон
€
Transcribed Image Text:Steric Hindrance Favors the Elimination Product However, if either the primary alkyl halide or the nucleophile/base is sterically hindered, then the nucleophile will have difficulty getting to the back side of the a-carbon but will be able to remove the more accessible proton. As a result, elimination will win the competition. the primary alkyl halide is sterically hindered Br + CH3O the nucleophile is sterically hindered Br + Xó 40% 15% + 60% 85% CH3OH + Br Хон €
Expert Solution
steps

Step by step

Solved in 5 steps with 3 images

Blurred answer
Knowledge Booster
Photochemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY