Which of the compounds shown most closely corresponds to the IR data: 3500-3200 cm (weak) and 2950-2850 cm ? Select the single best answer. NH OH NH₂ B 000 Ar > > A
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- The IR spectra for acetaminophen and phenacetin are shown below. a. Identify which spectrum is for acetaminophen and which is for phenacetin. b. Label the key bond/functional group signals on each spectrum. (e.g. N-H, C=O, O-H, C=C, C(sp3-H, C(sp³)–H) OH fou acetaminophen phenacetin 100.0 90 80 70 60 50 40 30 20 10 0.0 40000 3000 2000 1500 1000 4000 čm-1 LOD 4000 3000 2000 1500 1000 500 3305.35- 6891 1228.63- 117185 107.83-Methyl ethyl ether (shown below) has an -OCH 2 - group, an -OCH 3 - group, and a methyl group. The ' H NMR spectrum displays a quartet at 3.5 ppm, a signal at 3.0 ppm, and a signal at 1.2 ppm. Using the data in the table, what is the correct assignment of the spectrum? H H. H. Proton Environment Chemical Shift (8,ppm) Methylene, -C H 2 - 0.3 - 1.2 Methyl, -C H 3 1.1 - 1.9 Alkoxy, -OC H 2/3 3.3 - 4.0 -OC H 3 = 3.5 ppm (quartet), -OC H 2 = 3.0 ppm (singlet), -C H 3 = 1.2 ppm (triplet) -OC H 3 = 1.2 ppm (singlet), -OCH 2 3.5 ppm (quartet), -C H 3 = 3.0 ppm (triplet) -OC H 3 = 3.0 ppm (singlet), -OCH 2= 3.5 ppm (quartet), -C H 3 = 1.2 ppm (triplet) -OC H 3 = 3.5 ppm (quartet), -OC H 2 1.2 ppm (triplet), -C H 3 = 3.0 ppm (quartet) -OC H 3 = 1.2 ppm (singlet), -OCH 2= 3.0 ppm (doublet), -C H 3 = 3.5 ppm (quartet) -OC H 3 = 3.0 ppm (triplet), -OC H 2 = 3.5 ppm (quartet), -C H 3 = 1.2 ppm (triplet)Consider isomeric alcohols A and B and mass spectra [1] and [2]. (a) Label the molecular ion and base peak in each spectrum. (b) Use thefragmentation patterns to determine which mass spectrum correspondsto isomer A and which corresponds to isomer B.
- Which of the following compounds matches the given data? MS: base peak = 71 Mt= 105 ; M+2 = 107 (ratio 3:1) IR: 1782 cm-1 (strong), 1724 cm1 (strong) а) b) .N. c) Cl- d) N. ÓH PThe mass spectrum of an alcohol (C5H12O) exhibits a base peak at m/z =59. Is the alcohol most likely pentan-1-ol, pentan-2-ol, or pentan-3-ol? Explain.Final answer in skeletal form
- 8. What is the m/z values corresponding to the molecular ion and base peak for the following OH compound?When measured on a spectrometer operating at 200 MHz, chloroform (CHCl3) shows a single sharp absorption at 7.3 δ. (a) How many parts per million downfield from TMS does chloroform absorb? (b) How many hertz downfield from TMS would chloroform absorb if the measurement were carried out on a spectrometer operating at 360 MHz? (c) What would be the position of the chloroform absorption in δ units when measured on a 360 MHz spectrometer?Cyclohexnone exhibits its strongest IR absorption hand at 5.86 m, and at this wavelength there is a linear relationship between absorbance and concentration. (a) Identify the part of the molecule responsible for the absorbance at this wavelength. (b) Suggest a solvent that would be suitable for a quantitative analysis of cyclohexanone at this wavelength. (c) A solution of cyclohexanone (4.0 mg/mL) in the solvent selected in part (b) exhibits a blank-corrected absorbance of 0.800 in a cell with a path length of 0.025 mm. What is the detection limit for this compound under these conditions if the noise associated with the spectrum of the solvent is 0.001 absorbance units?
- Consider the following Proton and Carbon NMR spectra for the same compound, and it contains Chlorine. Decide on a structure which is consistent with the spectral data, and 'assign" both spectra as best as you can. "Assign" = draw structure, label (a,b,c etc) and indicate which peaks belong to which type.What functional group below gives IR signals at 1700 cm¹ and 2510-3000 cm¹? O Ketone O Amide Carboxylic Acid O Aldehyde O Alcohol PreviousB. MASS SPECTRUM Identify the following from the low resolution mass spectrum of the unknown compound: 100 Relative intensity LT. 80 80 60 40 20 Base peak 0 20 Molecular lon peak 40 Mass Spectrum of Compound P 121 152 60 C. DOUBLE BOND EQUIVALENTS Calculate the DBE of the unknown compound. m/z This information indicates, for example, the presence of 100 Mass spectrum of the compound. 120 140 160 a + x