In each row of the table below, select the stronger base. Select the stronger base: Select the stronger base: Select the stronger base: Select the stronger base: H O O N- H equally basic equally basic equally basic equally basic

In each row of the table below, select the stronger base. Select the stronger base: Select the stronger base: Select the stronger base: Select the stronger base: H O O N- H equally basic equally basic equally basic equally basic

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter4: Polar Bonds, Polar Reactions

Section: Chapter Questions

Problem 28CTQ: For the previous four questions, label each molecule that appears in the question or your answer...

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In each row of the table below, select the stronger base.

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(E) Label each of the following as strong acid, strong base, or neither.
Several acids and their respective equilibrium constants are: Which is the strongest acid? Which is the weakest acid? Which acid has the weakest conjugate base? Which acid has the strongest conjugate base?
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Consider the following four biological solutions: (1) bile, pH 8.0, (2) blood, pH 7.4, (3) urine, pH 6.0, and (4) gastric juice, pH 1.6. a. Which solution has the lowest [H3O+]? b. Which solution has the lowest [OH]? c. List the solutions in order of decreasing acidity. d. List the solutions in order of increasing basicity.
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A very strong base can remove a proton from methylamine:
Trimethylamine, (CH3)3N, reacts readily with diborane, B2H6. The diborane dissociates to two BH3 fragments, each of which can react with trimethylamine to form a complex, (CH3)3N:BH3. Write an equation for this reaction and interpret it in terms of Lewis acid-base theory.
The following are equivalent ways of asking about the acidity of an H atom: • What is the most acidic H on the molecule? • Which H is associated with the published pKa value? • Which H on the molecule is easiest to remove? • Which H on the molecule takes the least energy to remove? • Which bond to an H is most polarized? • For which H atom is removal least uphill in energy? • Which bond to an H atom, when broken, results in the lowest PE conjugate base? We will often find the last of these questions is easiest to answer. To do this, find all the different Hatoms on the molecule, and draw all possible conjugate bases.Only the lowest-energy one is the “real” conjugate base. Identify this structure, and you have found the most acidic H. Use this strategy to find the most acidic H on each of the following molecules. Note: Each structure hasat least three different kinds of H’s, so draw at least three unique conjugate bases for each.