33. The reaction I(aq) + OCI (aq) →10¯(aq) + CI¯¯(aq) was studied, and the following data were obtained: [-]。 [ocl-], (mol/L) (mol/L) Initial Rate (mol/L. s) 0.12 0.18 7.91 x 10-2 0.060 0.18 3.95 x 10-2 0.030 0.090 9.88 x 10-3 0.24 0.090 7.91 X 10-2 a. What is the rate law? b. Calculate the value of the rate constant. c. Calculate the initial rate for an experiment where both I- and OCI are initially present at 0.15 mol/L.

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Chapter11: Chemical Kinetics
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33. The reaction
I(aq) + OCI (aq) →10¯(aq) + CI¯¯(aq)
was studied, and the following data were obtained:
[-]。
[ocl-],
(mol/L)
(mol/L)
Initial Rate
(mol/L. s)
0.12
0.18
7.91 x 10-2
0.060
0.18
3.95 x 10-2
0.030
0.090
9.88 x 10-3
0.24
0.090
7.91 X 10-2
a. What is the rate law?
b. Calculate the value of the rate constant.
c. Calculate the initial rate for an experiment where both I-
and OCI are initially present at 0.15 mol/L.
Transcribed Image Text:33. The reaction I(aq) + OCI (aq) →10¯(aq) + CI¯¯(aq) was studied, and the following data were obtained: [-]。 [ocl-], (mol/L) (mol/L) Initial Rate (mol/L. s) 0.12 0.18 7.91 x 10-2 0.060 0.18 3.95 x 10-2 0.030 0.090 9.88 x 10-3 0.24 0.090 7.91 X 10-2 a. What is the rate law? b. Calculate the value of the rate constant. c. Calculate the initial rate for an experiment where both I- and OCI are initially present at 0.15 mol/L.
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