When equal molar amounts of phthalic anhydride and 1,2,3-propanetriol are heated, they form an amorphous polyester. Under these conditions, polymerization is regio- selective for the primary hydroxyl groups of the triol. OH heat + HO. LOH a polyester Phthalic anhydride 1,2,3-Propanetriol (Glycerol)
When equal molar amounts of phthalic anhydride and 1,2,3-propanetriol are heated, they form an amorphous polyester. Under these conditions, polymerization is regio- selective for the primary hydroxyl groups of the triol. OH heat + HO. LOH a polyester Phthalic anhydride 1,2,3-Propanetriol (Glycerol)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The polyester can be mixed with additional phthalic anhydride
(0.5 mole of phthalic anhydride for each mole of 1,2,3-propanetriol in the original
polyester) to form a liquid resin. When this resin is heated, it forms a hard, insoluble thermosetting polyester called glyptal.
Q.) Propose a structure for the repeat unit in glyptal.
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