5. Copolymers of the TAT monomer (shown below) have been prepared and studied for solar cell applications. The preparation of this monomer starts from a tetrahalogenated phenyl ring, which can be converted into the tetrathienophenyl intermediate shown using cross-coupling reactions. Identify this tetrahalogenated phenyl starting material, and demonstrate how it could be converted into the intermediate. C6H13 Br, C6H13 C6H2X4 X = F, CI, Br or I S- S- C6H13 C6H13 Br Intermediate tetrathienophenyl TAT monomer

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5. Copolymers of the TAT monomer (shown below) have been prepared and studied for solar cell
applications. The preparation of this monomer starts from a tetrahalogenated phenyl ring, which can
be converted into the tetrathienophenyl intermediate shown using cross-coupling reactions. Identify
this tetrahalogenated phenyl starting material, and demonstrate how it could be converted into the
intermediate.
C6H13
Br.
C6H13
C6H2X4
X = F, CI, Br or I
C6H13
C6H13
Br
Intermediate tetrathienophenyl
TAT monomer
Transcribed Image Text:Question: 5. Copolymers of the TAT monomer (shown below) have been prepared and studied for solar cell applications. The preparation of this monomer starts from a tetrahalogenated phenyl ring, which can be converted into the tetrathienophenyl intermediate shown using cross-coupling reactions. Identify this tetrahalogenated phenyl starting material, and demonstrate how it could be converted into the intermediate. C6H13 Br. C6H13 C6H2X4 X = F, CI, Br or I C6H13 C6H13 Br Intermediate tetrathienophenyl TAT monomer
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