Compound 4 has two functional groups and it will formed an oily yellow liquid when it reacts with nitrous acid. They discovered that compound B is produced during the halogenation process of compound A. When compound B is reacted with nitric acid, compound C is formed. While Friedel Crafts alkylation of compound A produces compound D. Compound E was produced by Friedel Crafts acylation of compound A. This compound E reacts positively with alkaline iodine and 2,4-dinitropheny hydrazine. However, it returns negative results for Tollens* and Benedict's tests. a) Illustrate the potential 1H NMR spectrum for compound A. b) Identify the possible structural formula of compound A (according to the carbon type) based on your proposed 13C NMR spectrum.
Compound 4 has two functional groups and it will formed an oily yellow liquid when it reacts with nitrous acid. They discovered that compound B is produced during the halogenation process of compound A. When compound B is reacted with nitric acid, compound C is formed. While Friedel Crafts alkylation of compound A produces compound D. Compound E was produced by Friedel Crafts acylation of compound A. This compound E reacts positively with alkaline iodine and 2,4-dinitropheny hydrazine. However, it returns negative results for Tollens* and Benedict's tests. a) Illustrate the potential 1H NMR spectrum for compound A. b) Identify the possible structural formula of compound A (according to the carbon type) based on your proposed 13C NMR spectrum.
Compound 4 has two functional groups and it will formed an oily yellow liquid when it reacts with nitrous acid. They discovered that compound B is produced during the halogenation process of compound A. When compound B is reacted with nitric acid, compound C is formed. While Friedel Crafts alkylation of compound A produces compound D. Compound E was produced by Friedel Crafts acylation of compound A. This compound E reacts positively with alkaline iodine and 2,4-dinitropheny hydrazine. However, it returns negative results for Tollens* and Benedict's tests. a) Illustrate the potential 1H NMR spectrum for compound A. b) Identify the possible structural formula of compound A (according to the carbon type) based on your proposed 13C NMR spectrum.
Compound 4 has two functional groups and it will formed an oily yellow liquid when it reacts
with nitrous acid. They discovered that compound B is produced during the halogenation
process of compound A. When compound B is reacted with nitric acid, compound C is formed.
While Friedel Crafts alkylation of compound A produces compound D. Compound E was
produced by Friedel Crafts acylation of compound A. This compound E reacts positively with
alkaline iodine and 2,4-dinitropheny hydrazine. However, it returns negative results for Tollens*
and Benedict's tests.
a) Illustrate the potential
1H NMR spectrum for compound A.
b) Identify the possible structural formula of compound A (according to the carbon type)
based on your proposed
13C NMR spectrum.
c) Predict the possible structural formula compounds B to E. The carbon atoms for
compound A should be more than SIX (6).
d) Distinguish between compound 4 with benzenedizonium chloride.
e) Predict the possible chemical reaction for formation of compounds B and E from
compound A and explain your answer.
f) Predict the possible chemical reaction for formation of compound C from compound
B and explain your answer.
g) Explain why compound E gives negative results for Tollens" and Benedict's tests.
h) Discuss why compound A formed an oily yellow liquid when it reacts with nitrous acid.
i)
With the aid of diagram, discuss the solubility of compound B and compound C and
identify which compound is the most soluble.
Definition Definition Group of atoms that shape the chemical characteristics of a molecule. The behavior of a functional group is uniform in undergoing comparable chemical reactions, regardless of the other constituents of the molecule. Functional groups aid in the classification and anticipation of reactivity of organic molecules.
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