Tutorial 10 - Selectivity and Reactivity of Enolate Reaction Worksheet 1. Predict the products that result when 2-cyclohexen-1-one is reacted with the following reagents. FL A NaCN, HCN 5-10 °C 1) (CH3CH2)2CuLi 2) H3O+ B PhNH2, toluene E 1) nBuLi, Et₂O 2) H3O+ 1) PhCH2MgBr 2) H3O+ OMe NaOMe, HOME
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- Predict the major products A- N for each of the following reactions. он NAOH 1) O3 D concd. H2SO4 в + heat 2) H2S 180°C NH,NH2 Кон (CH3)2CHOH Br2/FeBr3 KMNO4 F heat NaOH LIAIH4 SOCI, CH3O'Na* > K Br HBr K* "OC(CH3)3 t-BUOH ROOR (peroxide) Na* OCH3 CH3OHReagent 3 list; commas separate the choices benzylamine,cyclohexlbromide, cyclohexylamine NaBH3CN catalytic H+, h30, NaOH Reagent 4 list; CH3(Ch2)2MgBr, cyclohexylamine NaBH3CN catalytic H+, Na2 Cr2 O7 H2O H2SO4,cyclohexabromide reagent 5 list; cyclohexylamine NaBH3CN catalytic H+,CH3(Ch2)2MgBr, cyclohexabromide, benzylamineComplete the reaction scheme below. Show all reagents and intermediates. No reaction is a possible answer. 1) CH3CH2M9B CH3OH H+ (ехcess) но 2) H30*, H2O B A OCH3
- The following series of reactions will yield ___________. 1) CH3CH2SH + NaOH 2) Cl-CH2-CH2-C6H5 ortho-chloro-ethyl-benzene 2-chloro-4-ethyl-benzenesulfonic acid CH3CH2-S-CH2CH2C6H5 1-phenyl-3-chloro-propane CH3CH2-O-CH2CH2C6H5 Thank you!lotu PREDICT THE FINAL SEQUENCE OF REACTIONSSIL A) H-CEC-H n Navita B) H-CC-H 2) Mez 3) R2BH 4112021 NaOH 1) NaNz 2) Me D 3) NaNH2 4)6+2 5) Na, NH3 (1) 4.Choose the best reagents to complete the reaction shown below. HO 0= 0= OH e A B C D E 1.03 2. HOẠC mCPBA 2. H3O+ 1. Hg(OAc)2, H₂O 2. NaBH4, NaOH RCO3H 1. OsO4 (catalytic),
- Question 13 Propose best Williamson ether syntheses for the following compounds. Select all applicable options (multiple answers can be possible). Note: Some compounds cannot be made using Williamson synthesis reaction. ΚΗ A: + ⚫OH ΕΘ OK SN2 KH ΘΘ + -Br B: -OH OK SN1 C: ☐ A B ☐ C Cannot be synthesized using Williamson ether syntheses.Propose best Williamson ether syntheses for the following compounds. Select all applicable options (multiple answers can be possible). Note: Some compounds cannot be made using Williamson synthesis reaction. ـيـة A: -OH Na Na Br -Br SN2 Na CI B: -OH C: B ☐ C -CI Na O SN1 Cannot be synthesized using Williamson ether syntheses. MacBook Air 80 000 AA DII F3 F4 F5 F6 F7 F8 DD F9Question 14 Propose best Williamson ether syntheses for the following compounds. Select all applicable options (multiple answers can be possible). Note: Some compounds cannot be made using Williamson synthesis reaction. همه ΚΗ A: LOH ΘΘ OK Br SN2 Br NaH B: ⚫OH -ONa SN2 C: A B C Cannot be synthesized using Williamson ether syntheses.
- What sequence of reactions will transform the starting material shown into the product? N' 1) SOCI, 2) NaCN 3) H2, Raney Ni 4) CH3I (2 eq) (CH;CH2),NH, HCI (cat.), NaBH3CN 1) SOCI, 2) (CH3CH2),NH (> 2 eq) 3) LİAIH4 4) H30+ 1) LİAIH4 2) H3O+ 3) (CH3CH2)2NH , HCI (cat.), NaBH3CNThe following series of reactions will yield 2) CI-CH2-CH2-C6H5 1) CH3CH2SH + N2OH O 2-chloro-4-ethyl-benzenesulfonic acid O CH;CH2-S-CH2CH2C6H5 O ortho-chloro-ethyl-benzene O 1-phenyl-3-chloro-propane O CH3CH2-O-CH2CH2C6H51) LiAlH4; ) H3O+ will do which of the following reactions? 3-Phenyl-butanoic acid → 3-phenyl-butan-1-ol Benzene → cyclohexane Benzoic acid → benzaldehyde 2-Phenyl-hexanoic acid → benzoic acid and carbon dioxide 2,3-dimethyl-pent-1-yne → 2,3-dimethyl-pent-1-ene