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Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Identify the correct reagent/s for carrying out each of the following reactions shown below.

**Image Transcription: Chemical Reaction Pathways**

In this diagram, three distinct organic chemical reaction pathways are illustrated. Each reaction begins with a specific organic molecule and proceeds through a transformation to yield a final product. The reactions involve the use of different reagents, which are denoted by labeled rectangles and listed at the bottom of the diagram.

1. **First Reaction:**
   - **Starting Material:** A simple alkene (but-1-ene).
   - **Reagents:** Labeled as "A".
   - **Product:** A diol with hydroxyl groups added to adjacent carbon atoms (1,2-butane diol).

2. **Second Reaction:**
   - **Starting Material:** A substituted alkene (2,3-dimethyl-2-butene).
   - **Reagents:** Labeled as "B".
   - **Product:** A dihalide with chlorine atoms added (2,3-dichloro-2,3-dimethylbutane).

3. **Third Reaction:**
   - **Starting Material:** 1,2-cyclopentanediol, a cyclic diol.
   - **Reagents:** Labeled as "D".
   - **Product:** An open-chain dicarboxylic acid (adipaldehyde).

**Reagent Key:**
- **A:** Cl₂/H₂O (Chlorine in water) – used for halohydrin formation.
- **B:** CHCl₃/KOH (Chloroform and potassium hydroxide) – results in haloform-type reactions.
- **C:** 1. O₃/CH₂Cl₂ 2. Zn/H₃O⁺ (Ozonolysis followed by reductive workup) – splits double bonds.
- **D:** HIO₄/THF/H₂O (Periodic acid in tetrahydrofuran and water) – used for oxidative cleavage of vicinal diols.
- **E:** H₃O⁺/THF (Acid in tetrahydrofuran) – commonly used for acidic reactions.
- **F:** 1. OsO₄/pyridine 2. NaHSO₃ (Osmium tetroxide with pyridine, followed by sodium bisulfite) – used in syn dihydroxylation.

These pathways demonstrate the application of various reagents in organic chemistry to derive different functional groups and structures from similar
Transcribed Image Text:**Image Transcription: Chemical Reaction Pathways** In this diagram, three distinct organic chemical reaction pathways are illustrated. Each reaction begins with a specific organic molecule and proceeds through a transformation to yield a final product. The reactions involve the use of different reagents, which are denoted by labeled rectangles and listed at the bottom of the diagram. 1. **First Reaction:** - **Starting Material:** A simple alkene (but-1-ene). - **Reagents:** Labeled as "A". - **Product:** A diol with hydroxyl groups added to adjacent carbon atoms (1,2-butane diol). 2. **Second Reaction:** - **Starting Material:** A substituted alkene (2,3-dimethyl-2-butene). - **Reagents:** Labeled as "B". - **Product:** A dihalide with chlorine atoms added (2,3-dichloro-2,3-dimethylbutane). 3. **Third Reaction:** - **Starting Material:** 1,2-cyclopentanediol, a cyclic diol. - **Reagents:** Labeled as "D". - **Product:** An open-chain dicarboxylic acid (adipaldehyde). **Reagent Key:** - **A:** Cl₂/H₂O (Chlorine in water) – used for halohydrin formation. - **B:** CHCl₃/KOH (Chloroform and potassium hydroxide) – results in haloform-type reactions. - **C:** 1. O₃/CH₂Cl₂ 2. Zn/H₃O⁺ (Ozonolysis followed by reductive workup) – splits double bonds. - **D:** HIO₄/THF/H₂O (Periodic acid in tetrahydrofuran and water) – used for oxidative cleavage of vicinal diols. - **E:** H₃O⁺/THF (Acid in tetrahydrofuran) – commonly used for acidic reactions. - **F:** 1. OsO₄/pyridine 2. NaHSO₃ (Osmium tetroxide with pyridine, followed by sodium bisulfite) – used in syn dihydroxylation. These pathways demonstrate the application of various reagents in organic chemistry to derive different functional groups and structures from similar
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