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The reaction scheme below, proposed by students, will not work. Why not? HO -Br OH Mg HO -MgBr ether 1. cyclohexanone 2. mild H3O+ HO O The Grignard reagent will immediately react with the phenolic OH group, destroying the Grignard reagent before it can react with cyclohexanone. O The H30+ in the second step will destroy the erignard Reagent. O The H3O+ in the second step needs to be strong acid, because the Grignard reagent is a strong base. O Cyclohexanone is too sterically congested.

The reaction scheme below, proposed by students, will not work. Why not? HO -Br OH Mg HO -MgBr ether 1. cyclohexanone 2. mild H3O+ HO O The Grignard reagent will immediately react with the phenolic OH group, destroying the Grignard reagent before it can react with cyclohexanone. O The H30+ in the second step will destroy the erignard Reagent. O The H3O+ in the second step needs to be strong acid, because the Grignard reagent is a strong base. O Cyclohexanone is too sterically congested.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The reaction scheme below, proposed by students, will not work. Why not? HO -Br OH Mg HO -MgBr ether 1. cyclohexanone 2. mild H3O+ HO O The Grignard reagent will immediately react with the phenolic OH group, destroying the Grignard reagent before it can react with cyclohexanone. O The H30+ in the second step will destroy the erignard Reagent. O The H3O+ in the second step needs to be strong acid, because the Grignard reagent is a strong base. O Cyclohexanone is too sterically congested.
Transcribed Image Text:The reaction scheme below, proposed by students, will not work. Why not? HO -Br OH Mg HO -MgBr ether 1. cyclohexanone 2. mild H3O+ HO O The Grignard reagent will immediately react with the phenolic OH group, destroying the Grignard reagent before it can react with cyclohexanone. O The H30+ in the second step will destroy the erignard Reagent. O The H3O+ in the second step needs to be strong acid, because the Grignard reagent is a strong base. O Cyclohexanone is too sterically congested.
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