The values for effective diameters and activity coefficients for ions at 25°C are given in the table below. Activity Coefficient at Indicated Ionic Strength Ion ax, nm 0.001 0.005 0.01 0.05 0.1 Ca2+, Cu 2+, Zn2+, Sn2+, Mn2+, Fe 2+, Ni 2+, Co 2+, Phthalate² 0.6 0.870 0.748 0.676 0.48 0.40 Pb2+, CO2, SO32, C₂042 0.45 0.868 0.741 0.665 0.45 0.36 Al+, Fe 3+, Cr3+, La³+, Ce3+ 0.9 0.737 0.540 0.443 0.24 0.18 Th+, Zr, Ce+, Sn4+ 1.1 0.587 0.348 0.252 0.10 0.063 Use the Debye-Hückel equation 0.51Z√√ -log 7x= Yx 1+3.3ax√√ to calculate the activity coefficient of a. Fe3+ at = 0.024. Activity coefficient = b. Pb2+ at 0.013. Activity coefficient = Ce4+ c. Ce at 4 0.089. C. = Activity coefficient
The values for effective diameters and activity coefficients for ions at 25°C are given in the table below. Activity Coefficient at Indicated Ionic Strength Ion ax, nm 0.001 0.005 0.01 0.05 0.1 Ca2+, Cu 2+, Zn2+, Sn2+, Mn2+, Fe 2+, Ni 2+, Co 2+, Phthalate² 0.6 0.870 0.748 0.676 0.48 0.40 Pb2+, CO2, SO32, C₂042 0.45 0.868 0.741 0.665 0.45 0.36 Al+, Fe 3+, Cr3+, La³+, Ce3+ 0.9 0.737 0.540 0.443 0.24 0.18 Th+, Zr, Ce+, Sn4+ 1.1 0.587 0.348 0.252 0.10 0.063 Use the Debye-Hückel equation 0.51Z√√ -log 7x= Yx 1+3.3ax√√ to calculate the activity coefficient of a. Fe3+ at = 0.024. Activity coefficient = b. Pb2+ at 0.013. Activity coefficient = Ce4+ c. Ce at 4 0.089. C. = Activity coefficient
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:The values for effective diameters and activity coefficients for ions at 25°C are given in the table below.
Activity Coefficient at Indicated Ionic Strength
Ion
ax, nm
0.001
0.005
0.01
0.05
0.1
Ca2+, Cu 2+, Zn2+, Sn2+, Mn2+, Fe 2+, Ni 2+, Co 2+, Phthalate²
0.6
0.870
0.748
0.676
0.48
0.40
Pb2+, CO2, SO32, C₂042
0.45
0.868
0.741
0.665
0.45
0.36
Al+, Fe 3+, Cr3+, La³+, Ce3+
0.9
0.737
0.540
0.443
0.24
0.18
Th+, Zr, Ce+, Sn4+
1.1
0.587
0.348
0.252
0.10
0.063
Use the Debye-Hückel equation
0.51Z√√
-log 7x=
Yx
1+3.3ax√√
to calculate the activity coefficient of
a.
Fe3+
at = 0.024.
Activity coefficient =
b. Pb2+ at 0.013.
Activity coefficient =
Ce4+
c. Ce at 4 0.089.
C.
=
Activity coefficient
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