The rate of reaction of [0.1 M] sodium cyanide with [0.1 M] 1-bromo-heptane is 1.2 x 10-3 M/s. What would be the rate IF the concentration of sodium cyanide is increased to [0.233 M] and the concentration of the alkyl bromide is decreased to [0.05 3M]?
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![The rate of reaction of [0.1 M] sodium cyanide with [0.1 M] 1-bromo-heptane is
1.2 x 10-3 M/s.
What would be the rate IF the concentration of sodium cyanide is increased to
[0.233 M] and the concentration of the alkyl bromide is decreased to [0.05 3M]?](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F2f795fb7-90e0-4716-b28d-65224df888c5%2F99832e66-6b04-4515-aaa9-d2d8cf9ddbfb%2Fpq3mgd_processed.jpeg&w=3840&q=75)
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- What is the slow, rate-determining step, in the acid-catalyzed dehydration of 2- butanol? Loss of a b-hydrogen from the carbocation to form an alkene. Protonation of the alcohol to form an oxonium ion. Loss of water from the oxonium ion to form a carbocation. The simultaneous loss of a B-hydrogen and water from the oxonium ion.If the rate of reaction of [0.1 M] sodium cyanide with [0.1 M] 2- bromo-2-methylpropane is 1.2 mole/second, what would be the effect on the overall rate if the concentration of sodium cyanide is increased to [0.2 M] and the concentration of the alkyl bromide is decreased to [0.05 M]? H3C Br H3C CN + NaCN NaBr H3C CH3 H,C CH3 Provide a mechanistic explanation (using curly arrows) for the observed mixture of products in the following dehydration reaction (adding H2SO4), circle the major product, and state why you think it is the major product. OHThere is great excess of H2O in this reaction.
- Determine the type of mechanism for the following reaction and the rate law. Use R-Br to represent the alkyl halide in the rate equation.You determine the bimolecular rate constant k for a set of SN2 reactions. Based on your understanding of how the nucleophile effects the rate constant for an SN2 reaction, drag and drop the nucleophiles into the correct rows in the table below. Alkyl halide Nucleophile k / L mol-1 s-1 CI 0.011 -CI 0.045 0.074 0.095 -NH2 -NH2 >-NH2 -NH2 -NH27. The reaction of methoxide anion with bromoethane to yield the ether ethyl methyl ether and the bromide anon (Br-) is an excellent example of a general reaction type called Sy2 (substitution nucleophilic bimolecular): CH,0+ CH,СH-Br a CH3-0-CH,СH; + Br- a. Change in enthalpy is -103 kJ/mol; the change in entropy is + 0.025 kJ/mol-K. Calculate DG at 300K. b. Is the reaction endergonic or exergonic? c. Is the reaction endothermic or exothermic? d. Use curved arrows to show the complete mechanism. Reaction of 2-methyl-1-butene with H-Cl could yield TWO alkyl chloride products. Draw and name 8. them.
- If the rate of reaction of [0.1 M] sodium cyanide with [0.1 M] 2-bromo-2-methylpropane is 1.2 mole/second, what would be the effect on theoverall rate if the concentration of sodium cyanide is increased to [0.2 M] and the concentration of the alkyl bromide is decreased to [0.05 M]?Only one of the chlorine atoms in the molecule, 3,4-dichloronitrobenzene, will undergo nucleophilic substitution. Indicate which position will react and provide the expected product for the given reaction using reaction intermediates (resonance structures).Draw the organic product you would expect to isolate from the nucleophilic substitution reaction between the molecules shown. Note: You do not need to draw any of the side products of the reaction, only the substitution product. H × 5 Br + HO + 1 Click and drag to start drawing a structure.
- 4. A CHEM 245 student wants to synthesize some ethylene glycol to use as antifreeze in his radiator this winter. He proposes the following reaction to his instructor, who quickly explains that this reaction won't work as proposed due to the student's choice of reagent. 1) NaH 2) H20 OH Но a) Why can't sodium hydride (NaH) be used as the nucleophile in the reaction above? b) Propose an alternate reagent that COULD be used with the ethylene oxide to successfully give the desired ethylene glycol product.5-The hydrolysis of a series of ethyl benzoates by hydroxide ion in 85% aqueous ethanol has been investigated. A Hammett plot of the second order rate constants (K) gave a reaction constant p = 2.56. Calculate how much faster ethyl 4- nitrobenzoate will undergo base catalyzed hydrolysis compared to ethyl benzoate under similar conditions. O,NIn the substitution reaction of 2-chloro-2,4- dimethylpentane with water, the rate at which the alcohol product is formed depends on the concentration of the nucleophile. Select one: True False
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