Use Cahn-Ingold-Prelog rules to assign priority to the substituents on this molecule. A H D B H₂N C Substituent Priority Substituent A (Choose one) ▼ Substituent B (Choose one) ▼ Substituent C (Choose one) ▼ Substituent D (Choose one) ▼ G
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- Draw a resonance structure, complete with all formal charges and lone (unshared) electron pairs, that shows the resonance interaction of the acetoxy with the para position in phenyl acetate. phenyl acetate ● CH3 • You do not have to consider stereochemistry. • Include all valence lone pairs in your answer. In cases where there is more than one answer, just draw one. Sn [F ?Consider these compounds4. Assign Cahn–Ingold-Prelog rankings to the following sets of substituents: (a) –CH=CH2, –CH(CH3)2, –C(CH3)3, –CH2CH3 (b) — С—СН, — СH3CH2, —C(CH3)з, (c) –CO2CH3, –-COCH3, –CH2OCH3, –CH2CH3 (d) –C=N, –CH2B1, –CH2CH2Br, -Br
- Rank the following sets of substituents according to the Cahn-Ingold-Prelog sequence rules.Explain the fact that the C-O stretch in ethers and esters occurs at 1000-1100 cm-1 when the C is sp hybridized, but at 1250 cm- when it is sp2 hybridized.Account for the fact that among the chlorinated derivatives of methane, chloro- methane has the largest dipole moment and tetrachloromethane has the smallest dipole moment. Molecular Formula Dipole Moment (debyes, D) Name CH,CI CH,CI, Chloromethane 1.87 Dichloromethane 1.60 Trichloromethane CHCI, 1.01 Tetrachloromethane CCI,
- Esc smooth 0 CH₂- Ph -CH-CH3 (3) (CH3)3C-C=C—CH(CH3)CH₂CH3 CH3 5c CH₂-C=C-C-OH T CH₂CH3 CH3 C C-CH₂CH3 53-methyloct-4-yne H₂C CH3 H C=C-CH₂CH₂ CH3 -CBr₂ C=C-CH3 CH,–C=C–CH3 Ph-C=C-H (CH₂)₂C-C=C—CH(CH₂) CH₂CH3 Chapter 9 Alkynes Quiz 2 1. Name each molecule. 2. Use the molecules in the reactions 1 through 9 highlighted in red to determine the product. 3. Draw the line/angle or skeletal structure of eachmolecule. 4. Use the alkyne below to predict the products 1- 9.What is the IUPAC name for this molecule?A B C D E 1. NaBH4 2. H3O+ 1. CH3MgBr 2. H3O+ 1. (CH3)2CuLi 2. H3O+ 1. CH3Li 2. H3O+ 1. (CH3CH2)2CuLi 2. H3O+
- The boiling point of methylcyclohexane (C7H14, MW 98.2) is 101°C. The boiling point of perfluoromethylcyclohexane (C7F14, MW 350) is 76°C. Account for the fact that although the molecular weight of perfluoromethylcyclohexane is over three times that of methylcyclohexane, its boiling point is lower than that of methylcyclohexane.Alcohols can be converted to alkyl chlorides using SOCl2 with complete inversion of stereochemistry. Using curved arrows draw the stepwise mechanism for chlorination of an alcohol. Be sure to include lone pairs necessary to the mechanism steps and any non-zero formal charges.anome H₂C-CH₂ H₂C H₂C-CH₂ H₂C H₂C-CH₂ H₂C H₂C-CH₂ H₂C + B₁₂ C=CH-CH =CH-CH CH₂ CH₂ CH3 =CH-CH CH₂ CH₂ CH3 =CH-CH CH₂ FeBr3 CH₂ + Ch + HBr + H₂Oo + H₂ Pt