Reaction 2: (p) Consider the following reaction that proceeds via a concerted mechanism. Add arrows to indicate the movement of electrons. OCH3 OCH3 (e) The electrophile in the reaction in part (d) is ethylene (H2CCH2). Circle the orbital of the electrophile that must overlap with the nucleophile orbital in this reaction. (f) nonbonding lone pair nonbonding p σC-C OC-0 σC-H πC-C σ*C-C σ*C-0 σ*C-H π*C-C In going from reactants to products in the reaction in part (d), does entropy increase, decrease, or stay about the same?

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter8: Addition Via Carbocation
Section: Chapter Questions
Problem 8E
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Reaction 2:
(p)
Consider the following reaction that proceeds via a concerted mechanism. Add arrows
to indicate the movement of electrons.
OCH3
OCH3
(e)
The electrophile in the reaction in part (d) is ethylene (H2CCH2). Circle the orbital of the
electrophile that must overlap with the nucleophile orbital in this reaction.
(f)
nonbonding lone pair
nonbonding p
σC-C
OC-0
σC-H
πC-C
σ*C-C
σ*C-0
σ*C-H
π*C-C
In going from reactants to products in the reaction in part (d), does entropy increase,
decrease, or stay about the same?
Transcribed Image Text:Reaction 2: (p) Consider the following reaction that proceeds via a concerted mechanism. Add arrows to indicate the movement of electrons. OCH3 OCH3 (e) The electrophile in the reaction in part (d) is ethylene (H2CCH2). Circle the orbital of the electrophile that must overlap with the nucleophile orbital in this reaction. (f) nonbonding lone pair nonbonding p σC-C OC-0 σC-H πC-C σ*C-C σ*C-0 σ*C-H π*C-C In going from reactants to products in the reaction in part (d), does entropy increase, decrease, or stay about the same?
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