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- 4. Fill in the missing information (reactants, products, or reagents) in the following transformations. If more than one product is possible, draw structures for all products and indicate the major product. If stereoisomers are possible, draw all isomers, and indicate the major stereoisomer. + a. C. d. e. НО. НО. CI OH OH X PCC NaOCH HBr SOCI J.... CI OH FocusPredict the major products of both organic reactions. Be sure to use wedge and dash bonds to show the stereochemistry of the products when it's important, for example to distinguish between two different major products. + X H₂O Click and drag to start drawing a structure. + © A B 1. Hg (OAc)2, H₂O Click and drag to start drawing a structure. 2. NaBH4Predict whether each reaction proceeds predominantly by substitution (SN1 or SN2) or elimination (E1 or E2) or whether the two compete. Write structural formulas for the major organic product(s).
- CH3 CH3 Br- Br2 .CH3 CH2Cl2 CH3 H3C H3C Br Electrophilic addition of bromine, Brɔ, to alkenes yields a 1,2-dibromoalkane. The reaction proceeds through a cyclic intermediate known as a bromonium ion. The reaction occurs in an anhydrous solvent such as CH,Cl,. In the second step of the reaction, bromide is the nucleophile and attacks at one of the carbons of the bromonium ion to yield the product. Due to steric clashes, the bromide ion always attacks the carbon from the opposite face of the bromonium ion so that a product with anti stereochemistry is formed. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions CH3 CH3 CH3 CH3 H3C H3C :Br: :Br:HW11#5Draw the structural formula of the alkene that reacts with ozone followed by dimethyl sulfide to give product or set of products.
- Ff.138.(a) 2-methyl-2-pentanol Draw the structure of the alkene that was used to prepare the alcohol in highest yield. AAVIL ? ChemDoodleⓇ Which process does this employ? 1. Hg(OAc)2, H₂O; 2. NaBH4 01. BH3; 2. H₂O2, NaOH OsO4, H₂O2 On n [ ]#ces to access important values if needed for this question. Complete the equation for the following reaction by drawing a structural formula for the missing organic product. CH3CH2NH2 H20 CH,CH,C-OH • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Draw cations and anions in separate sketchers. P. opy aste C. [F Visited CH4 M) M) M) ChemDoodle Submit Answer Retry Entire Group 5 more group attempts remaining