Answered: V Arter running various experiments,… | bartleby

Organic Chemistry: A Guided Inquiry

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter13: Substitution

Section: Chapter Questions

Problem 43CTQ

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Question

V
Arter running various experiments, you determine that the rate law for the following reaction has a first-order dependence on the
concentration of the alkyl halide, and doesn't depend on the concentration of the other reactant at all.
Br
+ H₂O
OH2
+ Br
Using this information, draw the correct mechanism in the space below.
Explanation
Check
टे
Add/Remove step
Br
Click and drag to start
drawing a structure.
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Below is the equation for a nucleophilic substitution reaction and some experimental data. CH3CH2Br + CH3COO- ⇌ CH3CH2CO2CH3 + Br- Rate = k [CH3CH2Br][CH3COO-] Which mechanism would best fit the data?
Br tBuO H3C H3C CH2 H2 Alkyl halides undergo nucleophilic substitution and elimination reactions. When the kinetics of the reaction are measured, if the rate of the reaction is found alkyl halide the reaction is second order. The substitution reaction is thus termed SN2, and the elimination reaction is be dependent upon the concentration of the nucleophile as well as the termed E2. These reactions are bimolecular and take place in a single step. In the SN2 reaction, the nucleophile attacks the a-carbon from the backside and displaces the leaving group with an inversion of configuration occurring at the carbon. In the E2 elimination reaction, strong base removes an acidic hydrogen from the B-carbon and an alkene is formed as the leaving group is expelled from the a-carbon. This elimination follows Zaitsev's rule whereby the more substituted alkene is generally formed. In E2 elimination, both the B-hydrogen and the leaving group must be oriented anti to each other. The same reaction…
a) Sketch the energy diagram for the conversion of tertiary butyl bromide to methyl t-butyl ether. Note that this is a two step reaction with the t-butyl cation as an intermediate. Assume that this is overall an exothermic reaction. Show the location of both transition states and the intermediate. The first step has the higher energy of activation and is the rate determining step. (CH3)3C-Br ------> (CH3)3C+ + Br- (CH3)3C+ + H3CO- ------> (CH3)3C-O-CH3 (b)Draw the curved arrow mechanism and the transition state when the tertiary butyl carbocation reacts with the methoxide ion to give an ether. (CH3)3C+ + H3CO- ------> (CH3)3C-O-CH3
H₂C H H₁C Br NBS CH, CH₂ CC, hv **You may assume that Br-Br is formed by a side reaction that occurs (which we discussed in class). This is useful for one of the steps of the mechanism.
7. Condensation Polymers oliya + CI + H₂N. NH₂ H₂SO4 + n + nHCI n HCI For the second reaction above, show the full mechanism for one addition of the two monomers (3 steps).
A H2N. Figure 9: Multi-step reaction sequence
In an E2 mediated elimination reaction of an alkyl halide (H-X) using NaOCH3 as base, which of the following statement is not true? O The reactivity order for alkyl halides (RX) is tertiary secondary> primary. O The rate of reaction = k2 (alkyl halide] [NaOCH₂] O The reaction occurs in a single step. O The rate is independent of the leaving group.
ochem help... What is the product for the following three-step reaction sequence? Also, provide the structures or the major organic compounds formed in steps 1 and 2. (see attached image)
The correct answer is D, can you please draw the mechanism for the set of reactions shown? A. 1. H,O* 2. PBГ3 3. TMSCI, Et,N 4. Mg, Et,0 5. В. 1. HBr 2. Mg, Et,0 3. 4. Cro3, pyridine (excess) 6. Cro3, pyridine (excess) С. 1. HBr 2. TMSCI, Et,N 3. Mg, Et,0 o D. 1. HBr 2. TMSCI, Et,N 3. Mg, Et,0 4. 4. OMe 5. TBAF 6. CrO3, pyridine (excess) 5. TBAF 6. CrO3, pyridine (excess)
7
please do the mechanism. Identify which one is the nucleophile/electrophile. Name the reaction as well. Discuss the stereochemistry so why the dash bond go to wedged- due to inversion? Why is PPh3 used for selectivity ? Please answer all of my questions.
A Grades for Angela Winston: CHEM-2 0 0 C ← caps lock 52 Heavy rain soon A Choose the reagent(s) that would be most likely to complete this reaction. - . S Aktiv Chemistry alt app.101edu.co E # D م Aktiv Chemistry 8888 R ه الكاكاك الكاكاك الكاك G B H N ASUS VivoBook OOOO U ل Answered: se the reagent(s) that wou Question 11 of 27 - M الشان K alt L (1586) Oldies music playing from ctrl 1.OsO. (catalytic) 2 NMO Bra HO 1. BH-THE 2 H.O., NaOH الحالات الالالالالكاك الالالال الكاك تات 1. Hg(OAC), M.O 2. NaBH., NaOH ه + enter, shift

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