The following initial rate data are for the oxidation of arsenate ion by cerium(IV) ion in aqueous solution: Experiment 1 2 3 4 3- AsO 3³ + 2Ce¹+ + H₂O → AsO4³+ 2Ce³+ + 2H+ [ASO3³]₁ k= M 0.0414 0.0828 0.0414 0.0828 [Ce4+] M M-².s-1 Initial Rate, M-s-1 0.191 0.191 0.382 0.382 Complete the rate law for this reaction in the box below. Use the form k[A]" [B]", where '1¹ is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n. Rate = 0.000817 0.00163 0.00327 0.00654

Chemistry for Engineering Students
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Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.32PAE: 11.32 The following experimental data were obtained for the reaction 2A + 3 B—C + 2D [A](mol L 1)...
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The following initial rate data are for the oxidation of arsenate ion by
cerium(IV) ion in aqueous solution:
AsO 3³+ 2Ce¹+ + H₂O → AsO4³ + 2Ce³++ 2H+
Experiment
1
2
3
Rate =
3-
[AsO ³] [C¹+]
M
M
k=
0.0414
0.0828
0.0414
0.0828
0.191
0.191
0.382
0.382
Complete the rate law for this reaction in the box below.
Use the form k[A]™ [B]", where '1' is understood for m or n and
concentrations taken to the zero power do not appear. Don't enter 1
for m or n.
M-2.s-1
Initial Rate,
M.S-¹
0.000817
0.00163
0.00327
0.00654
Transcribed Image Text:The following initial rate data are for the oxidation of arsenate ion by cerium(IV) ion in aqueous solution: AsO 3³+ 2Ce¹+ + H₂O → AsO4³ + 2Ce³++ 2H+ Experiment 1 2 3 Rate = 3- [AsO ³] [C¹+] M M k= 0.0414 0.0828 0.0414 0.0828 0.191 0.191 0.382 0.382 Complete the rate law for this reaction in the box below. Use the form k[A]™ [B]", where '1' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n. M-2.s-1 Initial Rate, M.S-¹ 0.000817 0.00163 0.00327 0.00654
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