The following initial rate data are for the oxidation of arsenate ion by cerium(IV) ion in aqueous solution:\[ \text{AsO}_3^{3-} + 2 \text{Ce}^{4+} + \text{H}_2\text{O} \rightarrow \text{AsO}_4^{3-} + 2 \text{Ce}^{3+} + 2 \text{H}^+ \]| Experiment | \([\text{AsO}_3^{3-}]_0\), M | \([\text{Ce}^{4+}]_0\), M | Initial Rate, M·s\(^{-1}\) ||------------|----------------------|---------------------|-------------------------------|| 1 | 0.0311 | 0.145 | 0.000345 || 2 | 0.0622 | 0.145 | 0.000690 || 3 | 0.0311 | 0.290 | 0.00138 || 4 | 0.0622 | 0.290 | 0.00276 |Complete the rate law for this reaction in the box below.Use the form \(k[\text{A}]^m[\text{B}]^n\), where '1' is understood for \(m\) or \(n\) and concentrations taken to the zero power do not appear. Don't enter 1 for \(m\) or \(n\).Rate = \_\_\_\_\[ k = \_\_\_\_ \text{ M}^{-2} \cdot \text{s}^{-1} \]

The objective of the question is to determine the rate and rate constant for the reaction.The rate…

The following initial rate data are for the oxidation of arsenate ion by cerium(IV) ion in aqueous solution: Experiment 1 2 3 4 Rate k = AsO3³+ 2Ce4+. = 4+ [ASO3³] [C¹+] M M 0.0311 0.0622 0.0311 0.0622 3- + H₂O → AsO4³ + 2Ce³+ + 2H+ M-2.s -1 0 Complete the rate law for this reaction in the box below. Use the form k[A] [B]", where '1' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n. I 0.145 0.145 0.290 0.290 Initial Rate, -1 M.s 0.000345 0.000690 0.00138 0.00276

The following initial rate data are for the oxidation of arsenate ion by cerium(IV) ion in aqueous solution: Experiment 1 2 3 4 Rate k = AsO3³+ 2Ce4+. = 4+ [ASO3³] [C¹+] M M 0.0311 0.0622 0.0311 0.0622 3- + H₂O → AsO4³ + 2Ce³+ + 2H+ M-2.s -1 0 Complete the rate law for this reaction in the box below. Use the form k[A] [B]", where '1' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n. I 0.145 0.145 0.290 0.290 Initial Rate, -1 M.s 0.000345 0.000690 0.00138 0.00276

Chemistry for Engineering Students

4th Edition

ISBN:9781337398909

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter13: Electrochemistry

Section: Chapter Questions

Problem 13.101PAE

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