Consider the following mechanism for the oxidation of bromide ions by hydrogen peroxide in aqueous acid solution. H+ + H₂O₂ {H₂O+-OH) (rapid Elementary Step 1 equilibrium) Elementary Step 2 Elementary Step 3 Potential Energy ( Consider the reaction profile below. Approximate the AH for the overall reaction. Reacton Profie 360 280 160 140 100 (H₂O+-OH) + Br−→ HOBr + H+ + Br 60 0 HOBr + H₂O (slowest) Br₂ + H₂O (fast) Reaction Progress
Consider the following mechanism for the oxidation of bromide ions by hydrogen peroxide in aqueous acid solution. H+ + H₂O₂ {H₂O+-OH) (rapid Elementary Step 1 equilibrium) Elementary Step 2 Elementary Step 3 Potential Energy ( Consider the reaction profile below. Approximate the AH for the overall reaction. Reacton Profie 360 280 160 140 100 (H₂O+-OH) + Br−→ HOBr + H+ + Br 60 0 HOBr + H₂O (slowest) Br₂ + H₂O (fast) Reaction Progress
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Consider the following mechanism for the oxidation of bromide ions by
hydrogen peroxide in aqueous acid solution.
H+ + H₂O₂ {H₂O+-OH) (rapid
Elementary Step 1
equilibrium)
Elementary Step 2
Elementary Step 3
Potential Energy (
Consider the reaction profile below. Approximate the AH for the overall
reaction.
Reacton Profie
360
280
160
140
100
(H₂O+-OH) + Br−→
HOBr + H+ + Br
60
0
HOBr + H₂O (slowest)
Br₂ + H₂O (fast)
Reaction Progress
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