The following questions are based on the reaction and data below. Chlorine dioxide is a reddish yellow gas that dissolves in water. In basic solution this reaction takes place: 2CIO 2(aq) + 20H (aq) ClIO 2 (aq) + CIO 3 (aq) + H2O(). Based on the following data, determine the rate law and the value of the rate constant. Initial Concentrations Initial Rate [CIO2] [OH] (M/s 0.060 0.030 0.0248 0.020 0.030 0.00276 0.020 0.090 0.00828 What is the order of the reaction with respect to CIO 2? Fourth order Zero order Second order First order

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**Question 8**

The following questions are based on the reaction and data below.

Chlorine dioxide is a reddish yellow gas that dissolves in water. In basic solution, this reaction takes place:

\[ 2 \text{ClO}_2 (\text{aq}) + 2 \text{OH}^- (\text{aq}) \rightarrow \text{ClO}_2^- (\text{aq}) + \text{ClO}_3^- (\text{aq}) + \text{H}_2\text{O}(\text{l}) \]

Based on the following data, determine the rate law and the value of the rate constant.

| Initial Concentrations | Initial Rate (M/s) |
|------------------------|--------------------|
| [ClO\(_2\)] = 0.060 M  | [OH\(^-\)] = 0.030 M | 0.0248 |
| [ClO\(_2\)] = 0.020 M  | [OH\(^-\)] = 0.030 M | 0.00276 |
| [ClO\(_2\)] = 0.020 M  | [OH\(^-\)] = 0.090 M | 0.00828 |

What is the order of the reaction with respect to ClO\(_2\)?

- Fourth order
- Zero order
- Second order
- First order

---

**Explanation:**

To determine the reaction order with respect to each reactant, observe how changes in concentration affect the rate. For example:

- Compare experiments where only one reactant concentration changes while the other remains constant.
- Calculate the rate constant from the rate law once the orders are established.
Transcribed Image Text:**Question 8** The following questions are based on the reaction and data below. Chlorine dioxide is a reddish yellow gas that dissolves in water. In basic solution, this reaction takes place: \[ 2 \text{ClO}_2 (\text{aq}) + 2 \text{OH}^- (\text{aq}) \rightarrow \text{ClO}_2^- (\text{aq}) + \text{ClO}_3^- (\text{aq}) + \text{H}_2\text{O}(\text{l}) \] Based on the following data, determine the rate law and the value of the rate constant. | Initial Concentrations | Initial Rate (M/s) | |------------------------|--------------------| | [ClO\(_2\)] = 0.060 M | [OH\(^-\)] = 0.030 M | 0.0248 | | [ClO\(_2\)] = 0.020 M | [OH\(^-\)] = 0.030 M | 0.00276 | | [ClO\(_2\)] = 0.020 M | [OH\(^-\)] = 0.090 M | 0.00828 | What is the order of the reaction with respect to ClO\(_2\)? - Fourth order - Zero order - Second order - First order --- **Explanation:** To determine the reaction order with respect to each reactant, observe how changes in concentration affect the rate. For example: - Compare experiments where only one reactant concentration changes while the other remains constant. - Calculate the rate constant from the rate law once the orders are established.
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