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The allyl cation (drawn below) generally only reacts with nucleophiles at the outer carbons, not at the inner carbon. This is easy enough to rationalize based on a resonance argument, as the positive charge never shows up on the middle carbon. However, you should now be able to make a more sophisticated argument to rationalize this observation using molecular orbital theory. Give it a try! Include drawings Nu Nu Nu. Nu

The allyl cation (drawn below) generally only reacts with nucleophiles at the outer carbons, not at the inner carbon. This is easy enough to rationalize based on a resonance argument, as the positive charge never shows up on the middle carbon. However, you should now be able to make a more sophisticated argument to rationalize this observation using molecular orbital theory. Give it a try! Include drawings Nu Nu Nu. Nu

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The allyl cation (drawn below) generally only reacts with nucleophiles at the outer carbons, not at the inner carbon. This is easy enough to rationalize based on a resonance argument, as the positive charge never shows up on the middle carbon. However, you should now be able to make a more sophisticated argument to rationalize this observation using molecular orbital theory. Give it a try! Include drawings Nu Nu Nu. Nu
Transcribed Image Text:The allyl cation (drawn below) generally only reacts with nucleophiles at the outer carbons, not at the inner carbon. This is easy enough to rationalize based on a resonance argument, as the positive charge never shows up on the middle carbon. However, you should now be able to make a more sophisticated argument to rationalize this observation using molecular orbital theory. Give it a try! Include drawings Nu Nu Nu. Nu
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