Homework Help is Here – Start Your Trial Now!
Science
Chemistry
Step 1: Step 2: (E)-(1-(diphenylphosphoryl)but-2-en- 1-yl)lithium H Step 3: H Step 4: OH (S)-4-(2-(5-hydroxypentyl)-1,3-dioxolan-2-yl)-2-methylbutanal PPh₂ OH PPh₂ THE HMPA Ph₂ _OH PPh₂ ů OH H H o PPh₂ OH PPh₂ O_ O™ PPh₂ OH Li+ O=PPh₂ H 5-(2-((S,4E,6E)-3-methylocta-4,6-dien-1-yl)-1,3-dioxolan-2-yl)pentan-1-ol

Step 1: Step 2: (E)-(1-(diphenylphosphoryl)but-2-en- 1-yl)lithium H Step 3: H Step 4: OH (S)-4-(2-(5-hydroxypentyl)-1,3-dioxolan-2-yl)-2-methylbutanal PPh₂ OH PPh₂ THE HMPA Ph₂ _OH PPh₂ ů OH H H o PPh₂ OH PPh₂ O_ O™ PPh₂ OH Li+ O=PPh₂ H 5-(2-((S,4E,6E)-3-methylocta-4,6-dien-1-yl)-1,3-dioxolan-2-yl)pentan-1-ol

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
See similar textbooks
icon
Related questions
Question

I have attached the reaction and mechanism. So please discuss any stereochemistry issues or regioselectivity. Is  there any selectivity? Or by using PPh2 there is some selectivity?? I don't understand how much simpler I can make this question as it keeps getting rejected by experts.

THF, HMPA [HWE -> Diene] Oxide+Aldehyde] юH] 0 ОН PPh₂ у OH
Transcribed Image Text:THF, HMPA [HWE -> Diene] Oxide+Aldehyde] юH] 0 ОН PPh₂ у OH
Step 1: Step 2: (E)-(1-(diphenylphosphoryl)but-2-en- 1-yl) lithium H Step 3: H H Step 4: (S)-4-(2-(5-hydroxypentyl)-1,3-dioxolan-2-yl)-2-methylbutanal OH PPh₂ _OH PPh ₂ THE HMPA PPh- OH PPh₂ OH H H PPh₂ O_ PPh₂ OH O™ -PPh₂ OH Li+ O=PPh₂ H 5-(2-((S,4E,6E)-3-methylocta-4,6-dien-1-yl)-1,3-dioxolan-2-yl)pentan-1-ol
Transcribed Image Text:Step 1: Step 2: (E)-(1-(diphenylphosphoryl)but-2-en- 1-yl) lithium H Step 3: H H Step 4: (S)-4-(2-(5-hydroxypentyl)-1,3-dioxolan-2-yl)-2-methylbutanal OH PPh₂ _OH PPh ₂ THE HMPA PPh- OH PPh₂ OH H H PPh₂ O_ PPh₂ OH O™ -PPh₂ OH Li+ O=PPh₂ H 5-(2-((S,4E,6E)-3-methylocta-4,6-dien-1-yl)-1,3-dioxolan-2-yl)pentan-1-ol
Expert Solution
steps

Step by step

Solved in 3 steps with 1 images

SEE SOLUTIONCheck out a sample Q&A here
Blurred answer
Knowledge Booster
Selection Rules for Pericyclic Reactions
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
SEE MORE TEXTBOOKS