1) Fill in the boxes and blanks below. Provide stepwise mechanisms (curved arrows) for each reaction step (elementary step) filling in all intermediates and products. Complete the Rxn Coord. Diagram template corresponding to the 2nd Rxn and ensure it represents the expected thermodynamics and kinetics expected for this reaction. (please use scratch paper first) Rxn #1 :Cl: Me a mixture Et of stereo- isomers HÖ: Me Et H-CI: :0 Me Reaction type (rxn 1)? H.. Me Rate law (rxn 1)? rate = optically pure What type of stereisomeric products (rxn 1)? intermediate 1 intermediate 2 Mes: Na CH3CN (polar solvent) Rxn #2 optically pure product Rxn type (rxn 2)? regiochemistry? ladd o & o* orbitals involved Bate law (rxn 2)? rate = rxn progress in TS for rxn 2
1) Fill in the boxes and blanks below. Provide stepwise mechanisms (curved arrows) for each reaction step (elementary step) filling in all intermediates and products. Complete the Rxn Coord. Diagram template corresponding to the 2nd Rxn and ensure it represents the expected thermodynamics and kinetics expected for this reaction. (please use scratch paper first) Rxn #1 :Cl: Me a mixture Et of stereo- isomers HÖ: Me Et H-CI: :0 Me Reaction type (rxn 1)? H.. Me Rate law (rxn 1)? rate = optically pure What type of stereisomeric products (rxn 1)? intermediate 1 intermediate 2 Mes: Na CH3CN (polar solvent) Rxn #2 optically pure product Rxn type (rxn 2)? regiochemistry? ladd o & o* orbitals involved Bate law (rxn 2)? rate = rxn progress in TS for rxn 2
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Reactions of Ethers
Ethers (R-O-R’) are compounds formed by replacing hydrogen atoms of an alcohol (R-OH compound) or a phenol (C6H5OH) by an aryl/ acyl group (functional group after removing single hydrogen from an aromatic ring). In this section, reaction, preparation and behavior of ethers are discussed in the context of organic chemistry.
Epoxides
Epoxides are a special class of cyclic ethers which are an important functional group in organic chemistry and generate reactive centers due to their unusual high reactivity. Due to their high reactivity, epoxides are considered to be toxic and mutagenic.
Williamson Ether Synthesis
An organic reaction in which an organohalide and a deprotonated alcohol forms ether is known as Williamson ether synthesis. Alexander Williamson developed the Williamson ether synthesis in 1850. The formation of ether in this synthesis is an SN2 reaction.
Question
Transcribed Image Text:1) Fill in the boxes and blanks below. Provide stepwise mechanisms (curved arrows) for each reaction
step (elementary step) filling in all intermediates and products. Complete the Rxn Coord. Diagram template
corresponding to the 2nd Rxn and ensure it represents the expected thermodynamics and kinetics expected
for this reaction. (please use scratch paper first)
Rxn #1
:CI: Me
a mixture
Et of stereo-
isomers
Ме
Но:
:0
Et H-CI:
Ме
Reaction type (rxn 1)?
H..
Ме
Rate law (rxn 1)? rate =
optically
pure
What type of stereisomeric products (rxn 1)?
intermediate 1
intermediate 2
MeS: Na
CH3CN
(polar solvent)
Rxn
#2
E
optically pure
product
Rxn type (rxn 2)?
regiochemistry?
add o & o* orbitals involved
in TS for rxn 2
rxn progress
Rate law (rxn 2)? rate =
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