Draw the product of an SN2 reaction shown below. Use a dash or wedge bond to indicate stereochemistry of substituents on asymmetric centers. Ignore inorganic byproducts. NaSCH3 THE Br • Q
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- Identify the major product of the reaction of an alkene shown below. ||| 1. Hg(OAc)2, H2O 2. NaBH4, NaOH ....... ОН || IV ОН о, ОН1) RCO H 2) [H₂SOJ. ? Modify the given structure to draw the major product(s). Use the single bond tool to interconvert between double and single bonds. If a racemic mixture of enantiomers is expected, draw both enantiomers. Note: you can select a structure and use Copy and Paste to save drawing time. H₂C. OH th CH, CH₂ OH H₂C OH aff CH₂ CH₂ Edit DrawingH3C heat EtO- C=CI b a ELOH H3C ČH3 Consider the above reaction and draw the structures of products a and b. • You do not have to consider stereochemistry. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner.
- Predict the major substitution products of the following reaction. Br CH3 H20 H3C" • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If there is more than one major product possible, draw all of them. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu. opy aste ChemDoodleDraw the predominant product(s) of the following reactions including stereochemistry when it is appropriate. CH;CH,CH,CH,-CEC-H 1 HBr • Consider E/ Z stereochemistry of alkenes. • Do not show stereochemistry in other cases. If no reaction occurs, draw the organic startıng material Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple products usıng the + sign from the drop-down menu. C P. aste C. [F ChemDoodleFollow the curved arrows and draw the product of an SN2 reaction shown below. Include all lone pairs. Use wedge and dash bonds to indicate stereochemistry where appropriate. Ignore inorganic byproducts. :N=C: THF Drawing H3C H Br:
- Starting from the wedge-and-dash structure below (sighting down the indicated bond), rotate the back carbon to provide the structure in the conformation that will be capable of an E2 elimination. R/S stereochemistry is graded. H CI K H H3C |||| Drawing < |||| Q Atoms, Bonds and Rings Charges Tap a node to see suggestions. H H H H H Undo X Reset Remove Done RotateDraw the most stable resonance form for the intermediate in the following electrophilic substitution reaction. CH3 Br2 / FeBr3 • You do not have to consider stereochemistry. Include all valence lone pairs in your answer. • In cases where there is more than one answer, just draw one. OO. #[ ] در ChemDoodle CH3 BrCH3 CH₂CH₂C CHCH3 *%8 [.. You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • If there is more than one major product possible, draw all of them. • Separate multiple products using the + sign from the drop-down menu. H₂O ·OO ? Ⓡ ChemDoodle H₂SO4 ? [F <
- Part A || CH2=CH' CH3 Draw the molecules on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars. The single bond is active by default. Show the appropriate stereochemistry by choosing the dashed or wedged buttons and then clicking a bond on the canvas. EXP. CONT. H +) C CI Br Marvin JS [1] by O ChemAxon F P.+ O H₂C=CHCH₂Cl Consider the above reaction and draw the structures of products a and b. heat ? ChemDoodleⓇ Eto EtOH • You do not have to consider stereochemistry. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. ✪. Sn [F V b removeN(CH2CH3)3 + HNO3 --------> a.) rewrite the reaction using bond-line structure of reagents and products of the reaction b.) supply the curved arrows explaining the mechanism of the reaction