A) Draw the products of this reaction that agree with the product ratios at each temperature wher run either neat or in ether. Label each product as either endo or exo and be sure to indicate stereochemistry. 0.08 furan n-phenyl maleimide Time 7 days 7 days 20 days 7 days then 5 h Temp 0 °C ambient ambient 0 °C 60 °C A B 36 48 68a 43 49 41 23a 21 A + N-phenyl- maleimide (%) 14 11 ga 36 B) Draw the reaction coordinate diagram of this reaction. Label the products from part A, and provide a drawing of any transition states.
A) Draw the products of this reaction that agree with the product ratios at each temperature wher run either neat or in ether. Label each product as either endo or exo and be sure to indicate stereochemistry. 0.08 furan n-phenyl maleimide Time 7 days 7 days 20 days 7 days then 5 h Temp 0 °C ambient ambient 0 °C 60 °C A B 36 48 68a 43 49 41 23a 21 A + N-phenyl- maleimide (%) 14 11 ga 36 B) Draw the reaction coordinate diagram of this reaction. Label the products from part A, and provide a drawing of any transition states.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:The ratio between the products resulting from the reversible Diels-Alder reaction of furan and N-
phenyl maleimide can be tuned by varying the reaction temperature and solvent. Please answer
the following questions.
A) Draw the products of this reaction that agree with the product ratios at each temperature when
run either neat or in ether. Label each product as either endo or exo and be sure to indicate
stereochemistry.
Q
furan n-phenyl maleimide
+
Time
7 days
7 days
20 days
7 days
then 5 h
Temp
0 °C
ambient
ambient
0 °C
60 °C
A B
36
49
48
41
68a 23a
43
21
A
+
N-phenyl-
maleimide
(%)
14
11
ga
36
B) Draw the reaction coordinate diagram of this reaction. Label the products from part A, and
provide a drawing of any transition states.
B
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