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![Since the pk values of aspartic acid
are 2.0, 3.9 and 10.0, aspartate
predominant species at pH=2.95:
a. [-1]
b. No charge
O c.[-2]
d. [+1]](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fa5bcab15-46ca-4e5b-a7d3-4c70d5b32390%2Fa5d87696-dbc9-4199-8f8a-e7703a289e17%2Fmmmxmu_processed.jpeg&w=3840&q=75)
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- What is the concentration of B expressed in terms of A if the Kd is 33.0 uM, and the concentration of AB is 56.0 uM? A + B AB OB= 1850/A OB= 23 - A OB=23+ A OB= 0.589/AQuinine ( C20 H24 N2 O2) is the most important alkaloid derived from cinchona bark. It is used as an antimalarial drug. For quinine, pK, = 5.1 and pK, = 9.7 ( pKp = – log Kp). Only 1 g quinine will dissolve in 1920.0 mL of solution. Calculate the pH of a saturated aqueous solution of quinine. Consider only the reaction | Q+ H2O= QH+ + OH- described by pK, where Q = quinine. pH =In vitro experiments are conducted at pH = 7.4 to simulate physiological conditions. A phosphate buffer system is often used. H₂PO → H₂PO¹²¯ +H+ pK₁ = 7.2 a. What must be the ratio of the concentrations of HPO to H₂POд ions? b. What mass of NaH2PO4 must be added to 500.0 mL of 0.10 M Na₂HPO4 (aq) in the preparation of the buffered solution?
- The conversion of glucose-1-phosphate to glucose-6-phosphate by the enzyme phosphoglucomutase has a △G°' of -7.6 kJ/mol. Calculate the equilibrium constant for this reaction at 298 K and a pH of 7. (R = 8.315 J/K-mol) A. 0.003 B. 0.047 C. 1.00 D. 21Aerobic degradation of an organic compound by mixed cultureof organism in wastewater can be represented by following reaction. C3H6O3 + a O2 + b NH3 → c C5H7NO2 + d H2o + e CO2 A. Determine a, b, c, d and e, if YX/S = 0.4 d X/g S. B. Determine the yield coefficients YX/O2 and YX/NH3. C. Determine the degree of reductions for the substrate, bacteria and RQ for the organisms1. Draw an approximate titration curve for lysine, given that its pKa(COOH) = 2.18, its pKa(NH3*) = 8.95, and its pka(R) = 10.53. a. What pH ranges would Lys be a good buffer at? b. What is the pl of Lys? C. Draw the structures of the predominant species in solution at (i) pH 0, (ii) pH 7, (iii) pH 9.5, (iv) pH 12.
- Given the titration curve of the hypothetical polyprotic acid X at 0.100 M concentration (pKa1=4.0, pKa2=8.0, pKa3=12.0) titrated with 0.600 M NaOH, identify the pH at point C, H, E, and M.A monoprotic weak acid, HA, dissociates in water according to the reaction HA(aq) = H*(aq) + A¯(aq) The equilibrium concentrations of the reactants and products are [HA] = 0.290 M, H+| = 3.00 × 10¬4 M, and [A-] = 3.00 x 10-4 M. Calculate the value of pKa for the acid HA. pKaFor an acid HA, the concentrations of HA and A are 0.075 and 0.025, respectively, at pH 6.0. What is the p K a value for HA?
- Consider a buffer solution of acetate. The volume is 500 ml, the concentration is 200 mM, and the pH is 5.0. a. How many total moles of acetate plus acetic acid are present in the solution? Express answer as x.y with one digit before and one after the decimal place. b. What is the ratio of acetate ions (Ac-) to acetic acid ions (HAc) in the buffer solution (pH 5.0) if the pka is 4.76? Express the answer as x.yz with one digit before and two after the decimal place. c. How many moles of acetate are present in the solution? Express your answer to one decimal place. d. How many moles of acetic acid are present in the solution? Express your answer to one decimal place.A monoprotic weak acid, HA, dissociates in water according to the reaction HA(aq) = H+ (aq) + A¯(aq) The equilibrium concentrations of the reactants and products are [HA] = 0.220 M, [H+] = 3.00 × 10−4 M, and [A¯] = 3.00 × 10−4 M. Calculate the value of pKa for the acid HA. pKa =At 39.9ºC, a solution of ethanol (XetOH = 0.9006, P * etOH = 130.4 Torr) and isooctane (P * iso = 43.9 Torr) forms a vapor phase with YetOH = 0.6667. The total pressure is 185.9 a. Calculate the activity and the activity coefficient of each component.b. Calculate the total pressure the solution would have if it were ideal.c. Comparing the ideal pressure to the actual pressure, what does this indicate about the molecular interactions?