The melting points of a series of 18-carbon fatty acids are: stearic acid, 69.6 °C; oleic acid, 13.4 °C; linoleic acid, −5 °C; and linolenic acid, −11 °C.(a) What structural aspect of these 18-carbon fatty acids can be correlated with the melting point?(b) Draw all the possible triacylglycerols that can be constructed from glycerol, palmitic acid, and oleic acid. Rank them in order of increasing melting point.(c) Branched-chain fatty acids are found in some bacterial membrane lipids. Would their presence increase or decrease the fluidity of the membrane (that is, give the lipids a lower or higher melting point)? Why?
The melting points of a series of 18-carbon fatty acids are: stearic acid, 69.6 °C; oleic acid, 13.4 °C; linoleic acid, −5 °C; and linolenic acid, −11 °C.(a) What structural aspect of these 18-carbon fatty acids can be correlated with the melting point?(b) Draw all the possible triacylglycerols that can be constructed from glycerol, palmitic acid, and oleic acid. Rank them in order of increasing melting point.(c) Branched-chain fatty acids are found in some bacterial membrane lipids. Would their presence increase or decrease the fluidity of the membrane (that is, give the lipids a lower or higher melting point)? Why?
Biochemistry
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ISBN:9781319114671
Author:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Publisher:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Chapter1: Biochemistry: An Evolving Science
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The melting points of a series of 18-carbon fatty acids are: stearic acid, 69.6 °C; oleic acid, 13.4 °C; linoleic acid, −5 °C; and linolenic acid, −11 °C.
(a) What structural aspect of these 18-carbon fatty acids can be correlated with the melting point?
(b) Draw all the possible triacylglycerols that can be constructed from glycerol, palmitic acid, and oleic acid. Rank them in order of increasing melting point.
(c) Branched-chain fatty acids are found in some bacterial membrane lipids. Would their presence increase or decrease the fluidity of the membrane (that is, give the lipids a lower or higher melting point)? Why?
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Step 1: Effect of unsaturation on fatty acid melting point
VIEWStep 2: (a) Structural relationship between the 18 carbon fatty acids and their melting points
VIEWStep 3: (b) Triacylglycerol combinations and their order of melting point
VIEWStep 4: (c) Effect of branched chain fatty acids on membrane fluidity
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