Ship BOARD [Review Topica) [References) Use the References to access important values if needed for this question. a. Use strain energy increments in the OWL Table Reference (see References button, Strain Energy Increments) to calculate the energy difference between the two chair conformations of the compound below. b. Specify substituent positions (axial or equatorial) in the more stable chair. c. Estimate the percent of the more stable chair at equilibrium at 25°C. (To determine the percent of the more stable chair at equilibrium, first calculate Keor and then use this value to find the percentage.) CH3 OH (in isopropanol) Answers: a. The energy difference is b. In the more stable chair: kJ/mol. o The methyl group is in the o The hydroxyl group is in the e position. 8 position. c. At 25°C the equilibrium percent of the more stable chair conformation is approximately Submit Answer Retry Entire Group 9 more group attempts remaining Previous Next Show Hint

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
Paraphrasingewriting Tool Car note Pirate Ship BLACKBOARD
[Review Topics)
[References)
Use the References to access important values if needed for this question.
a. Use strain energy increments in the OWL Table Reference (see References button, Strain Energy Increments)
to calculate the energy difference between the two chair conformations of the compound below.
b. Specify substituent positions (axial or equatorial) in the more stable chair.
c. Estimate the percent of the more stable chair at equilibrium at 25°C.
(To determine the percent of the more stable chair at equilibrium, first calculate Keor and then use
this value to find the percentage.)
CH3
OH
(in isopropanol)
Answers:
a. The energy difference is
kJ/mol.
b. In the more stable chair:
o The methyl group is in the
o The hydroxyl group is in the
O position.
e position.
C. At 25°C the equilibrium percent of the more stable chair conformation is approximately
Submit Answer
Retry Entire Group
9 more group attempts remaining
Previous
Next
Show Hint
Save and Exit
15
tv
MacBook Air
888
DII
DD
F3
F4
F5
F6
F7
F9
F10
F11
F12
$
%
&
4
5
6
7
8
9
dele
T
Y
U
{
11
F
G
H
J
K
L
<>
V
B
INI M
+ II
.. .-
Transcribed Image Text:Paraphrasingewriting Tool Car note Pirate Ship BLACKBOARD [Review Topics) [References) Use the References to access important values if needed for this question. a. Use strain energy increments in the OWL Table Reference (see References button, Strain Energy Increments) to calculate the energy difference between the two chair conformations of the compound below. b. Specify substituent positions (axial or equatorial) in the more stable chair. c. Estimate the percent of the more stable chair at equilibrium at 25°C. (To determine the percent of the more stable chair at equilibrium, first calculate Keor and then use this value to find the percentage.) CH3 OH (in isopropanol) Answers: a. The energy difference is kJ/mol. b. In the more stable chair: o The methyl group is in the o The hydroxyl group is in the O position. e position. C. At 25°C the equilibrium percent of the more stable chair conformation is approximately Submit Answer Retry Entire Group 9 more group attempts remaining Previous Next Show Hint Save and Exit 15 tv MacBook Air 888 DII DD F3 F4 F5 F6 F7 F9 F10 F11 F12 $ % & 4 5 6 7 8 9 dele T Y U { 11 F G H J K L <> V B INI M + II .. .-
Expert Solution
Step 1

Here by using strain energy increment of groups in chair conformation , we have to determine the strain energy difference, most stable chair an Equilibrium mole percentage of most stable chair conformation.

steps

Step by step

Solved in 3 steps with 2 images

Blurred answer
Knowledge Booster
Alkanes and Cycloalkanes
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY