a. Use strain energy increments in the OWL Table Reference (see References button, Strain Energy Increments) to calculate the energy difference between the two chair conformations of the compound below. b. Specify substituent positions (axial or equatorial) in the more stable chair. c. Estimate the percent of the more stable chair at equilibrium at 25°C. (To determine the percent of the more stable chair at equilibrium, first calculate Keg and then use this value to find the percentage.) CH3 H3C он Answers: a. The energy difference is kJ/mol.
a. Use strain energy increments in the OWL Table Reference (see References button, Strain Energy Increments) to calculate the energy difference between the two chair conformations of the compound below. b. Specify substituent positions (axial or equatorial) in the more stable chair. c. Estimate the percent of the more stable chair at equilibrium at 25°C. (To determine the percent of the more stable chair at equilibrium, first calculate Keg and then use this value to find the percentage.) CH3 H3C он Answers: a. The energy difference is kJ/mol.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Use the References to access important values if needed for
this question.
a. Use strain energy increments in the OWL
Table Reference (see References button,
Strain Energy Increments) to calculate the
energy difference between the two chair
conformations of the compound below.
b. Specify substituent positions (axial or
equatorial) in the more stable chair.
c. Estimate the percent of the more stable chair
at equilibrium at 25°C.
(To determine the percent of the more
stable chair at equilibrium, first calculate
Keg and then use this value to find the
percentage.)
CH3
H3C
HO.
Answers:
a. The energy difference is
kJ/mol.
b. In the more stable chair:
o The isopropyl group is in the
O position.
o The carboxyl group is in the
O position.
c. At 25°C the equilibrium percent of the more
stable chair conformation is approximately
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