Set up the rate expressions for the following reaction mechanism: A 2 B B +C 3 D If the concentration of B is small compared with the concentrations of A, C, and D, the steady-state approximation may be used to derive the rate law of the overall reaction. 1. Show that this reaction may follow the first-order reaction with [A] at high concentrations (or excess) of [C] kith k3>> k2. 2. Under this high concentrations (or excess) of [C] with k3 >> k2, graph the concentrations of [A], [B], and [D] vs time. Assume the initially only A and C exist in the system.
Set up the rate expressions for the following reaction mechanism: A 2 B B +C 3 D If the concentration of B is small compared with the concentrations of A, C, and D, the steady-state approximation may be used to derive the rate law of the overall reaction. 1. Show that this reaction may follow the first-order reaction with [A] at high concentrations (or excess) of [C] kith k3>> k2. 2. Under this high concentrations (or excess) of [C] with k3 >> k2, graph the concentrations of [A], [B], and [D] vs time. Assume the initially only A and C exist in the system.
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![Set up the rate expressions for the following reaction mechanism:
k
A 2 B
B + C D
If the concentration of B is small compared with the concentrations of A, C, and D, the steady-state approximation may be used to
derive the rate law of the overall reaction.
1. Show that this reaction may follow the first-order reaction with [A] at high concentrations (or excess) of [C] ith k3 >> k2.
2. Under this high concentrations (or excess) of [C] with k3 >> k2, graph the concentrations of [A], [B], and [D] vs time. Assume
the initially only A and C exist in the system.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fcfd09306-b295-4463-99d5-04e94ba1b6ad%2F2684efb7-bde3-408d-8bd1-23043e2516e6%2F8dokfo9_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Set up the rate expressions for the following reaction mechanism:
k
A 2 B
B + C D
If the concentration of B is small compared with the concentrations of A, C, and D, the steady-state approximation may be used to
derive the rate law of the overall reaction.
1. Show that this reaction may follow the first-order reaction with [A] at high concentrations (or excess) of [C] ith k3 >> k2.
2. Under this high concentrations (or excess) of [C] with k3 >> k2, graph the concentrations of [A], [B], and [D] vs time. Assume
the initially only A and C exist in the system.
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