k >R* + X¯ k_1 R* +Y¯ -→RY k2 Derive a rate law for the overall equation from the mechanism assuming the steady- state approximation in any intermediates. Only species in the overall reaction should appear in your final expression.
k >R* + X¯ k_1 R* +Y¯ -→RY k2 Derive a rate law for the overall equation from the mechanism assuming the steady- state approximation in any intermediates. Only species in the overall reaction should appear in your final expression.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:k
>R* + X¯
k_1
R* +Y¯ -→RY
k2
Derive a rate law for the overall equation from the mechanism assuming the steady-
state approximation in any intermediates. Only species in the overall reaction should
appear in your final expression.
Expert Solution
Step 1: Overall reaction
The overall reaction corresponding to the given multistep reaction is derived as shown below:
Clearly, R+ is an intermediate in the given multistep reaction.
So, the steady-state approximation is applicable for R+
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