15. Set up the rate expressions for the following mechanism k3 k A + B7 >C В +С-> D k2 If the concentration of B is small compared with the concentration of A, C and D, the steady-state approximation may that this reaction may follow the first-order equation at high pressures and the second-order equation at low be used to derive the rate law. Show pressure.

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Chapter1: Chemical Foundations
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15. Set up the rate expressions for the following
mechanism
B + c» D
k3
A + B C
k2
If the concentration of B is small compared with the
concentration of A, C and D, the steady-state
approximation may be used to derive the rate law. Show
that this reaction may follow the first-order equation at
high pressures and the second-order equation at low
pressure.
Transcribed Image Text:15. Set up the rate expressions for the following mechanism B + c» D k3 A + B C k2 If the concentration of B is small compared with the concentration of A, C and D, the steady-state approximation may be used to derive the rate law. Show that this reaction may follow the first-order equation at high pressures and the second-order equation at low pressure.
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