roposed mechanism: 3 K₁ K-₁ +03 0₂ + O K₂ Questions: 20₂ 2 03 3 0₂ (fast equilibrium) (much slower irrev. step) (net rxn, gas phase) Experimental Observations: • Double initial [03] ==> rate inc • Add [O₂] initially ==> rate drop (1) What is the chemical flux eqn for the proposed mechanism in terms of +d[0₂] (2) What is the SSA eqn for [O]? (3) What is the derived rate law for this mechanism in terms of +d[0₂]/dt? (4) Based on the exptl observations and derived overall rate law, is the proposed mechanism a plausible one for this rxn?

roposed mechanism: 3 K₁ K-₁ +03 0₂ + O K₂ Questions: 20₂ 2 03 3 0₂ (fast equilibrium) (much slower irrev. step) (net rxn, gas phase) Experimental Observations: • Double initial [03] ==> rate inc • Add [O₂] initially ==> rate drop (1) What is the chemical flux eqn for the proposed mechanism in terms of +d[0₂] (2) What is the SSA eqn for [O]? (3) What is the derived rate law for this mechanism in terms of +d[0₂]/dt? (4) Based on the exptl observations and derived overall rate law, is the proposed mechanism a plausible one for this rxn?

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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