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What compound is most consistent with the following mass spectrum? (choose the best structure shown below)
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- Calculate the molar extinction coefficient (e) of a molecule at a particular wavelength given that a 0.000764 M solution of the molecule produced a fluorescence intensity (I) of 1177 when the irradiance of the beam incident to the sample (Po) was 821 and the length of the medium (b) was 1.12 cm. The proportionality constant k' for this molecule is 0.319. € = ×10 TOOLS M-1.cm-1The observed fluorescence lifetime in the absenceof a quencher is 1.4 ns. In the presence of a quencher thefluorescence lifetime is 0.8 ns. Calculate the quenching efficiency. which is the ratio of the fluorescence quantum yieldsin the presence and absence of the quencher. ¢,/¢,_019
- For an enzyme reaction followed spectrophotometrically at 340 nm the Vmax was calculated at 0.14 ∆A340/min (ε340 = 5.22 mM-1.cm-1). The 1 mL reaction in a 1 cm cuvette contained 30 ng of an enzyme (Mr of 100 000 g/mole). Calculate the Kcat for this enzyme.An amino acid on the surface of an enzyme was labelled covalently with 1.5-I AEDANS and it is known that the active site contains a tryptophan residue. The fluorescence quantum yield of tryptophan decreased by 15 per cent due to quenching by 1.5-I AEDANS. What is the distance between the active site and the surface of the enzyme?A 25.0 mL aliquot was taken from a 500.0 mL sample of tonic water containing an unknown amount of quinine and diluted to a volume of 200 mL. At 347.5 nm, the fluorescence intensity of the diluted sample was measured 85.7 an arbitrary scale. Under similar conditions, a 27.5 ppm standard quinine solution had a fluorescence intensity of 185. Calculate the mass of quinine in the original tonic water sample in mg. Do not include units in your answer.
- E11A.5(a) The following data were obtained for the absorption at 450 nm by a dye in carbon tetrachloride when using a 2.0 mm cell. Calculate the molar absorption coefficient of the dye at the wavelength employed: [dye]/(mol dm³) T/(per cent) 0.0010 0.0050 0.0100 0.0500 81.4 35.6 12.7 3.0 x 10-3/x/Isl.exe/lo_u-IgNslkr7j8P3jH-IQs_dp5pR4ENzvdYC-70kXyMz36BqJhw3sVPj_jpaFLxvGArYxlbmayqa71YYPJBG6RjdYAdGPjGhFLILID-HEX1YcqAB?1oBw7QYjlbavbSPXtx-YCjsh_7mMmrq#item P Course Home Login | Student Veri... Hb Logout MyProgrammingLab Imported From IE O ITEC2110:Summer2... TunesToTube - Upl.. Publix App Web Development.. O KINETICS AND EQUILIBRIUM Using the Arrhenius equation to calculate k at one temperature fr. Cia 23%#3%# The rate constant of a certain reaction is known to obey the Arrhenius equation, and to have an activation energyE=45.0 kJ/mol. If the rate constant of this -1 -1 reaction is 4.4 x 10 M s at 266.0 °C, what will the rate constant be at 177.0 °C? Round your answer to 2 significant digits. -1 k = \\M -1 x10/Isl.exe/lo_u-IgNSIkr7j8P3jH-IQs_dp5pR4ENzvdYC-70kXyMz36Bqhw3sVPj_jpaFLxvGArYxlbmcyqa71YYPJBG6RjdYAdGPjGhFLILID-HEX1YcqAB?1oBw7QYjlbavbSPXtx-YCjsh_7mMmrq#3 P Course Home Login | Student Veri... Bb Logout MyProgrammingLab Imported From IE ITEC2110:Summer2... TunesToTube - Upl.. Web Development.. Pub O KINETICS AND EQUILIBRIUM Using a second-order integrated rate law to find concentration c.. Consider this reaction: 2HI (g) → H, (g) +I, (g) At a certain temperature it obeys this rate law. rate = (0.118 M-s)[H] ? Suppose a vessel contains HI at a concentration of 1.48 M. Calculate the concentration of HI in the vessel 42.0 seconds later. You may assume no other reaction is important. Round your answer to 2 significant digits. x10 II
- Radiation of wavelength 280 nm passed through 1.0 mm of a solution that contained an aqueous solution of the amino acid tryptophan at a concentration of 0.50 mmol dm-3 . The intensity of the rad iation is reduced to 54 per cent of its init ial va lue (so T = 0.54). Calcu late the molar absorpt ion coefficient and the absorbance of tryptophan at 280 nm. What would be the transmittance through a cell of thickness 2.0 mm?Infrared Spectroscopy (IR) is very useful for determining the functional groups present in an organic molecule. For each of the spectra below, complete the following: • Build the molecule in Spartan and describe the motion of the molecule at each key absorption frequency • Identify key absorption frequencies in the spectrum and identify the type of stretch/bend/wag/etc. (i.e. O-H) • Match the spectra from the provided structures • Identify the main functional groups in the molecule OH A OH H B E F H N NH2the spectra is of a drug either cannabinoid, opiate, MDMA etc, please explain the spectra and what drug could it be
