Question 1: (a) pK, of 4-methoxybenzenethiol was measured in DMSO, water, MeOH and MeOH/water (50/50%) mixture. Arrange the solvents in the order of increasing acidity, and explain your order. SH MẹO

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which solvent will make this compound more acidic. 
Question 1:
(a) pk, of 4-methoxybenzenethiol was measured in DMSO, water,
MEOH and MeOH/water (50/50%) mixture. Arrange the solvents in the
order of increasing acidity, and explain your order.
HS
Meo
(b) Draw a Hammett plot for the equilibrium acidities of substituted benzenethiols in DMSO and
water. Your graph should clearly indicate depict whether there is (or not) a difference (slope,
sign, anything) between DMSO and water.
Transcribed Image Text:Question 1: (a) pk, of 4-methoxybenzenethiol was measured in DMSO, water, MEOH and MeOH/water (50/50%) mixture. Arrange the solvents in the order of increasing acidity, and explain your order. HS Meo (b) Draw a Hammett plot for the equilibrium acidities of substituted benzenethiols in DMSO and water. Your graph should clearly indicate depict whether there is (or not) a difference (slope, sign, anything) between DMSO and water.
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