Homework Help is Here – Start Your Trial Now!
Science
Chemistry
Predict the direction of equilibrium in the following reaction. Explain your answer. O NH₂ + NH3

Predict the direction of equilibrium in the following reaction. Explain your answer. O NH₂ + NH3

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
See similar textbooks
icon
Related questions
icon
Concept explainers
Question
**Predict the direction of equilibrium in the following reaction. Explain your answer.** **Reaction:** - **Reactants:** - Compound with two carbonyl groups (indicated by two double-bonded oxygen atoms to adjacent carbon atoms) - An anionic amine group (\(NH_2^-\)) - **Products:** - Resonance-stabilized enolate ion (indicated by a carbonyl group and an additional negative charge) - Ammonia (\(NH_3\)) **Explanation:** In this reaction, the equilibrium direction can be predicted based on the relative acidity of the reactants and products. The equilibrium will generally favor the formation of the weaker acid and stronger base pair. - The doubly carbonyl-containing compound is relatively acidic due to its resonance stabilization capabilities when deprotonated, forming an enolate. - The \(\text{NH}_2^-\) is a strong base, while \(\text{NH}_3\) is a relatively weak acid. The reaction will thus likely favor the products side, as the enolate ion is resonance-stabilized and \(\text{NH}_3\) is a weaker acid compared to the starting carbonyl compound, making this equilibrium shift to the right.
Transcribed Image Text:**Predict the direction of equilibrium in the following reaction. Explain your answer.** **Reaction:** - **Reactants:** - Compound with two carbonyl groups (indicated by two double-bonded oxygen atoms to adjacent carbon atoms) - An anionic amine group (\(NH_2^-\)) - **Products:** - Resonance-stabilized enolate ion (indicated by a carbonyl group and an additional negative charge) - Ammonia (\(NH_3\)) **Explanation:** In this reaction, the equilibrium direction can be predicted based on the relative acidity of the reactants and products. The equilibrium will generally favor the formation of the weaker acid and stronger base pair. - The doubly carbonyl-containing compound is relatively acidic due to its resonance stabilization capabilities when deprotonated, forming an enolate. - The \(\text{NH}_2^-\) is a strong base, while \(\text{NH}_3\) is a relatively weak acid. The reaction will thus likely favor the products side, as the enolate ion is resonance-stabilized and \(\text{NH}_3\) is a weaker acid compared to the starting carbonyl compound, making this equilibrium shift to the right.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 1 images

SEE SOLUTIONCheck out a sample Q&A here
Blurred answer
Knowledge Booster
Ionic Equilibrium
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
SEE MORE TEXTBOOKS