Electronic Effects
The effect of electrons that are located in the chemical bonds within the atoms of the molecule is termed an electronic effect. The electronic effect is also explained as the effect through which the reactivity of the compound in one portion is controlled by the electron repulsion or attraction producing in another portion of the molecule.
Drawing Resonance Forms
In organic chemistry, resonance may be a mental exercise that illustrates the delocalization of electrons inside molecules within the valence bond theory of octet bonding. It entails creating several Lewis structures that, when combined, reflect the molecule's entire electronic structure. One Lewis diagram cannot explain the bonding (lone pair, double bond, octet) elaborately. A hybrid describes a combination of possible resonance structures that represents the entire delocalization of electrons within the molecule.
Using Molecular Structure To Predict Equilibrium
Equilibrium does not always imply an equal presence of reactants and products. This signifies that the reaction reaches a point when reactant and product quantities remain constant as the rate of forward and backward reaction is the same. Molecular structures of various compounds can help in predicting equilibrium.
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**Question:** Which of the following compounds is a stronger base: \((CH_3)_4NOH\) or \((CH_3)_3NHOH\)? Explain.
### Explanation for an Educational Website
Both compounds are bases and contain nitrogen atoms. The basicity of a compound can often be predicted by examining the presence of nitrogen and its surrounding groups.
1. **Tetramethylammonium Hydroxide (\((CH_3)_4NOH\)):**
- This compound is a quaternary ammonium hydroxide.
- It has four methyl groups attached to the nitrogen, making it a strong base.
- The lack of hydrogen atoms directly attached to the nitrogen reduces the possibility of hydrogen bonding, often increasing basicity.
2. **Trimethylhydroxylamine (\((CH_3)_3NHOH\)):**
- This compound has three methyl groups and one hydroxyl group attached to the nitrogen.
- The presence of the hydroxyl group can lead to hydrogen bonding, which might slightly reduce its basic nature compared to \((CH_3)_4NOH\).
**Conclusion:**
Typically, \((CH_3)_4NOH\) would be the stronger base because the presence of more alkyl groups that stabilize the positive charge on the nitrogen makes it a better electron pair donor. The presence of the hydroxyl group in \((CH_3)_3NHOH\) might cause hydrogen bonding, which can slightly decrease its basicity."
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