Part B Calculate the nonequilibrium concentration of ethanol in yeast cells, if AG = -38.3 kJ/mol for this reaction at pH = 7.4 and 37 °C when the reactants and products are at the concentrations given above. Express your answer with the appropriate units. μA Concentration = Value Submit Request Answer Units ?

Biochemistry
9th Edition
ISBN:9781319114671
Author:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Publisher:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Chapter1: Biochemistry: An Evolving Science
Section: Chapter Questions
Problem 1P
icon
Related questions
Question

3-2.23

solve part b

Part B
Calculate the nonequilibrium concentration of ethanol in yeast cells, if AG = −38.3 kJ/mol for this reaction at pH = 7.4 and 37 °C when the reactants and
products are at the concentrations given above.
Express your answer with the appropriate units.
HÅ
Concentration = Value
Submit
Request Answer
Units
?
Transcribed Image Text:Part B Calculate the nonequilibrium concentration of ethanol in yeast cells, if AG = −38.3 kJ/mol for this reaction at pH = 7.4 and 37 °C when the reactants and products are at the concentrations given above. Express your answer with the appropriate units. HÅ Concentration = Value Submit Request Answer Units ?
For part B of this problem, use the following standard reduction potentials, free energies, and nonequilibrium concentrations of reactants and products:
ADP
220 μΜ
ATP = 3.10 mM
glucose = 5.10 mM
NAD+ = 350 μM
P₁ = 5.90 mM
pyruvate = 62.0 µM
NADH = 15.0 μM
Part A
>0
half reaction
<0
Submit
-
CO₂: = 15.0 torr
NAD+ + H+ + 2e¯
2pyruvate + 6H+ + 4e¯
Consider the last two steps in the alcoholic fermentation of glucose by brewer's yeast:
pyruvate + NADH + 2H+
Do you predict that ASO for this reaction is > 0 or < 0?
Previous Answers
→ NADH
→glucose
→ ethanol + NAD+ + CO₂
ATP + H₂O → ADP + P; +H+
E° (V)
-0.315
-0.590
AGO = -64.4 kJ/mol
AGO = -32.2 kJ/mol
pyruvate + NADH+ 2H+ → ethanol + NAD+ + CO₂
Correct
As written 4 reactants combine to produce 3 products (there are 2 mol H+ as written, thus there are 4 reactants). Typically, producing fewer products than
reactants would require a loss of entropy; however, in this case one of the products is a gas (and none of the reactants are gases). Gas formation is
typically associated with a significant increase in entropy. Thus, the prediction that the entropy change is > 0 is reasonable.
Transcribed Image Text:For part B of this problem, use the following standard reduction potentials, free energies, and nonequilibrium concentrations of reactants and products: ADP 220 μΜ ATP = 3.10 mM glucose = 5.10 mM NAD+ = 350 μM P₁ = 5.90 mM pyruvate = 62.0 µM NADH = 15.0 μM Part A >0 half reaction <0 Submit - CO₂: = 15.0 torr NAD+ + H+ + 2e¯ 2pyruvate + 6H+ + 4e¯ Consider the last two steps in the alcoholic fermentation of glucose by brewer's yeast: pyruvate + NADH + 2H+ Do you predict that ASO for this reaction is > 0 or < 0? Previous Answers → NADH →glucose → ethanol + NAD+ + CO₂ ATP + H₂O → ADP + P; +H+ E° (V) -0.315 -0.590 AGO = -64.4 kJ/mol AGO = -32.2 kJ/mol pyruvate + NADH+ 2H+ → ethanol + NAD+ + CO₂ Correct As written 4 reactants combine to produce 3 products (there are 2 mol H+ as written, thus there are 4 reactants). Typically, producing fewer products than reactants would require a loss of entropy; however, in this case one of the products is a gas (and none of the reactants are gases). Gas formation is typically associated with a significant increase in entropy. Thus, the prediction that the entropy change is > 0 is reasonable.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps with 2 images

Blurred answer
Similar questions
Recommended textbooks for you
Biochemistry
Biochemistry
Biochemistry
ISBN:
9781319114671
Author:
Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Publisher:
W. H. Freeman
Lehninger Principles of Biochemistry
Lehninger Principles of Biochemistry
Biochemistry
ISBN:
9781464126116
Author:
David L. Nelson, Michael M. Cox
Publisher:
W. H. Freeman
Fundamentals of Biochemistry: Life at the Molecul…
Fundamentals of Biochemistry: Life at the Molecul…
Biochemistry
ISBN:
9781118918401
Author:
Donald Voet, Judith G. Voet, Charlotte W. Pratt
Publisher:
WILEY
Biochemistry
Biochemistry
Biochemistry
ISBN:
9781305961135
Author:
Mary K. Campbell, Shawn O. Farrell, Owen M. McDougal
Publisher:
Cengage Learning
Biochemistry
Biochemistry
Biochemistry
ISBN:
9781305577206
Author:
Reginald H. Garrett, Charles M. Grisham
Publisher:
Cengage Learning
Fundamentals of General, Organic, and Biological …
Fundamentals of General, Organic, and Biological …
Biochemistry
ISBN:
9780134015187
Author:
John E. McMurry, David S. Ballantine, Carl A. Hoeger, Virginia E. Peterson
Publisher:
PEARSON