One method of producing propylene is the dehydrogenation of propane C3H8 to proplene C3H6 according to the reaction C3H8-->C3H6+H2 A schematic of the reaction is shown below. The fresh feed (Stream 1) has a total flow rate of 100. mol/min and is composed of 96 mol% propane and 4.0 mol% propylene. The single pass conversion of propane across the reactor is 40% and all of the hydrogen is separated in the flash drum. Stream 5 exiting the flash drum is fed to a distillation column where 90% of the propylene is separated. The product (Stream 6) exiting the distillation column is composed of 99 mol% propylene and 1.0 mol% propane. The second stream exiting the column (Stream 7) is recycled back into the process. a) Why is there no purge stream for this process?  b) What is the overall conversion of propane?  c) What is the molar flow rate of propane in Stream 2?  d) What is the molar flow rate of propylene in Stream 7?  e) What is the recycle to fresh feed ratio f) Suggest 2 possible reasons why the single pass conversion of propane is relatively low.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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One method of producing propylene is the dehydrogenation of propane C3H8 to proplene C3H6 according to the reaction

C3H8-->C3H6+H2

A schematic of the reaction is shown below. The fresh feed (Stream 1) has a total flow rate of 100. mol/min and is composed of 96 mol% propane and 4.0 mol% propylene. The single pass conversion of propane across the reactor is 40% and all of the hydrogen is separated in the flash drum. Stream 5 exiting the flash drum is fed to
a distillation column where 90% of the propylene is separated. The product (Stream 6) exiting the distillation column is composed of 99 mol% propylene and 1.0 mol% propane. The second stream exiting the column (Stream 7) is recycled back into the process.
a) Why is there no purge stream for this process? 
b) What is the overall conversion of propane? 
c) What is the molar flow rate of propane in Stream 2? 
d) What is the molar flow rate of propylene in Stream 7? 
e) What is the recycle to fresh feed ratio
f) Suggest 2 possible reasons why the single pass conversion of propane is
relatively low. 

Stream 1
100. mol/min
96% Propane
4.0% Propylene
Stream 2
Reactor
Stream 7
Stream 3
Flash
drum
Stream 5
Stream 4
100.% Hydrogen
Column
Stream 6
1.0% Propane
99% Propylene
Transcribed Image Text:Stream 1 100. mol/min 96% Propane 4.0% Propylene Stream 2 Reactor Stream 7 Stream 3 Flash drum Stream 5 Stream 4 100.% Hydrogen Column Stream 6 1.0% Propane 99% Propylene
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