n a study of the gas phase decomposition of hydrogen peroxide at 400 °C H2O2(g)H2O(g) + ½ O2(g) the concentration of H2O2 was followed as a function of time. It was found that a graph of 1/[H2O2] versus time in seconds gave a straight line with a slope of 1.03 M-1 s-1 and a y-intercept of 13.4 M-1. Based on this plot, the reaction is (frist, second, zero)__________   order in H2O2 and the rate constant for the reaction is _____________ M-1 s-1.

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section: Chapter Questions
Problem 70GQ
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In a study of the gas phase decomposition of hydrogen peroxide at 400 °C

H2O2(g)H2O(g) + ½ O2(g)

the concentration of H2O2 was followed as a function of time.

It was found that a graph of 1/[H2O2] versus time in seconds gave a straight line with a slope of 1.03 M-1 s-1 and a y-intercept of 13.4 M-1.

Based on this plot, the reaction is (frist, second, zero)__________   order in H2O2 and the rate constant for the reaction is _____________ M-1 s-1.

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