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me proposed mechanism for the formation of phosgene (COC12) can be written in a simplified form as: Cl₂(g) Part A What rate law corresponds to this mechanism? k₁ k5 [CO]³/2 [C1₂] k3 K₁ K₂ k5 O k5 Oks k4 k₂ k3 k₁ k3 K₁ K₂ k¹ [CO][C1₂]³/2 [CO][C1₂]³/2 k₁ k₂ k3 k1 [CO]³/2 [C1₂] 2C1(g) Cl(g) + CO(g) COCI(g) k4 COCI(g) + Cl₂(g) → COC12 (g) + Cl(g) ks k₂ Fast Fast Slow

me proposed mechanism for the formation of phosgene (COC12) can be written in a simplified form as: Cl₂(g) Part A What rate law corresponds to this mechanism? k₁ k5 [CO]³/2 [C1₂] k3 K₁ K₂ k5 O k5 Oks k4 k₂ k3 k₁ k3 K₁ K₂ k¹ [CO][C1₂]³/2 [CO][C1₂]³/2 k₁ k₂ k3 k1 [CO]³/2 [C1₂] 2C1(g) Cl(g) + CO(g) COCI(g) k4 COCI(g) + Cl₂(g) → COC12 (g) + Cl(g) ks k₂ Fast Fast Slow

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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he proposed mechanism for the formation of phosgene (COC12) can be written in a simplified form as: Cl₂ (g) Part A What rate law corresponds to this mechanism? k3 k5 [CO]3/2 [C1₂] k4 kı k₂ 2 [CO][C1₂13/2 kı OK √ K3K¹ [CO][Cl₂13/2 K₁ K₂ KS TOV F K2CO³/2 [C1₂] kı Cl(g) + CO(g) COCI(g) + Cl₂ (g) 2 k4 → ks 2Cl(g) COCI(g) COC1₂(g) + Cl(g) Fast Fast Slow
Transcribed Image Text:he proposed mechanism for the formation of phosgene (COC12) can be written in a simplified form as: Cl₂ (g) Part A What rate law corresponds to this mechanism? k3 k5 [CO]3/2 [C1₂] k4 kı k₂ 2 [CO][C1₂13/2 kı OK √ K3K¹ [CO][Cl₂13/2 K₁ K₂ KS TOV F K2CO³/2 [C1₂] kı Cl(g) + CO(g) COCI(g) + Cl₂ (g) 2 k4 → ks 2Cl(g) COCI(g) COC1₂(g) + Cl(g) Fast Fast Slow
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