Initial temp: 19.06 C trial 1: 0.5 M concentration trial 2 : 1.0 M concentration 200 mL of HCl and 200 mL of NaOH are combined in an insulated container. HCl = 0.5 mol/ml x 200 x 10^-3 ml = 0.1 mol NaOH =  0.5 mol/ml x 200 x 10^-3 ml= 0.1 mol H+(aq) + OH-(aq) - - -> H2O (l) ∆H H++ = 0, ∆H OH−− = -230 kJ/mol, ∆H H2O = -286 kJ/mol ∆H reactants = ∆H H++ + ∆H OH−− = -230 + 0 = -230 kJ/mol ∆H reactants = -286 kJ/mol - ( -230 kJ/mol) = -56 kJ/mol   For each trial, calculate how much energy is released during this reaction.

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Initial temp: 19.06 C

trial 1: 0.5 M concentration

trial 2 : 1.0 M concentration

200 mL of HCl and 200 mL of NaOH are combined in an insulated container.

HCl = 0.5 mol/ml x 200 x 10^-3 ml = 0.1 mol

NaOH =  0.5 mol/ml x 200 x 10^-3 ml= 0.1 mol

H+(aq) + OH-(aq) - - -> H2O (l)

∆H H++ = 0, ∆H OH−− = -230 kJ/mol, ∆H H2O = -286 kJ/mol

∆H reactants = ∆H H++ + ∆H OH−−

= -230 + 0

= -230 kJ/mol

∆H reactants = -286 kJ/mol - ( -230 kJ/mol)

= -56 kJ/mol

 

For each trial, calculate how much energy is released during this reaction.

Expert Solution
Step 1 : Energy Released In Trial 1

trial 1: 0.5 M concentration

200 mL of HCl and 200 mL of NaOH are combined in an insulated container.

No of moles of HCl (n[HCl] ) = (0.5 mole/L) x (200 x 10-3 L) = 0.1 mole

No of moles of Na OH ( n[NaOH] ) = (0.5 mole/L) x (200 x 10-3 L) = 0.1 mole

0.1 H+(aq.) + 0.1 OH-(aq.) - - -> 0.1H2O (l)

∆H (H+) = 0,

∆H (OH) = -230 kJ/mole,

∆H (H2O) = -286 kJ/mole

∆Hreactants = n[HCl] * ∆H (H+)  +  n[NaOH] * ∆H (OH)

                      = (0.1 * 0)kJ/mole  + 0.1 * -230 kJ/ mole 

                      = -23 kJ/ mole 

∆Hproducts= n[H2O] * ∆H (H2O)  

                      = (0.1 * -286 )kJ/mole  

                      = -28.6kJ/ mole 

∆Hreaction =   ∆Hproducts  -  ∆Hreactants 

                 = [-28.6-(-23)] kJ/mole

                  = -5.6 kJ/mole 

energy is released during this reaction (Trial 1) = -5.6 kJ/mole

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