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Organic Chemistry: A Guided Inquiry

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter24: Carboxylic Acids & Derivatives

Section: Chapter Questions

Problem 12CTQ

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Tag the carbons in this molecule that are bonded to the H atoms that could be most easily abstracted by a radical reaction step. That is, find and
tag the carbons with the C-H bonds that are the most easily cleaved homolytically.
X
D
C

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The following molecules are subject to substitution (SN1 or SN2) reaction conditions. a) Identify if the leaving group (-Br) is attached to a 3°, 2°, 1°, or methyl Carbon. b) Rank the molecule with respect to their SN1 reactivity, with 1 being the fastest and 4 being the slowest. c) Rank the molecule with respect to their SN2 reactivity, with 1 being the fastest and 4 being the slowest. Br Br CH3B Br a. type of Carbon on C-Br b. SN1 reactivity (1 fastest, 4 slowest) c. SN2 reactivity (1 fastest, 4 slowest)
For the given molecule, highlight any nucleophilic sites in red and any electrophilic sites in blue. ୮
Fill the blank space. Compounds containing a phenol group may work as ANTIOXIDANTS to prevent free radical damage. This is accomplished when a free radical (or UV light) encounters a phenol group, turning the phenol group into a radical. However, contrary to typical radical behavior, the structure of the phenol radical can neutralize (or quench) the unpaired electron. Specifically, the phenol structure neutralizes (or quenches) the unpaired radical electron by doing the following: taking the electron and ---------. The correct name (or abbreviation) of an example compound containing a phenol group with antioxidant properties is: ---------.
Hello can someone check my answers please. I am kind of confused.
Draw all resonance structures that result from electrophilic attack at the ortho, meta, and para positions to the CH3 group
Draw a curved arrow mechanism for the substitution reaction that will occur with the alkyl halide and nucleophile below, adding steps as necessary. Be sure to include all nonbonding electrons and all nonzero formal charges, and show all species that react or are formed in this reaction.
please just answer for the given reaction
Please draw out fully do not use abbreviations such as CO2Me i don't know how to draw it
Complete the following nucleophilic substitution reactions. In each reaction, show all electron pairs on both the nucleophile and the leaving group.
For the given SN2 reaction, draw the organic and inorganic products of the reaction, and identify the nucleophile, substrate, and leaving group. Include wedge-and-dash bonds and draw hydrogen on a stereocenter. Hmm.. CEN + CI Organic product Inorganic product
1
Label all of the nucleophilic and electrophilic sites on the following molecule НО. NH₂

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