How many seconds will it take for Ca2+ and BR- to migrate 35.0 cm in a field of 4750 V/m? The mobilities are 6.12 x 10^-8 m^2/Vs for Ca2+ and 8.13 x 10^-8 m^2/Vs for Br-
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- The equation to calculate for molar absorptivity (ε) is ε = A/(bc) where A is absorbance (unitless), b is path length in cm, and c is concentration in M. Suppose you have a solution with concentration of 2.9 ± 0.25 M, a path length of 1 ± 0.1 cm, and an absorbance of 0.4629 ± 0.0006. What is the uncertainty or error for the molar absorptivity?. The conductance of 0.00017 M acetic acid solution is 153 µS when applying a probe with 0.87 cm−1cell constant. The same probe measures 5.7 µS for the conductance of water. Calculate the conductivityand molar conductivity of the solution.Chloroform is an internal standard in the determination of the pesticide DDT in a polarographic analysis in which each compound is reduced at an electrode surface. A mixture containing 0.500 mM chloroform and 0.800 mM DDT gave signals of 15.3 µA for chloroform and 10.1 µA for DDT. An unknown solution (10.00 mL) containing DDT was placed in a 100-ml volumetric flask and 10.2 ul of chloroform (MW = 119.39, density = 1.484 g/mL) were added. After dilution to the mark with solvent, polarographic signals of 29.4 and 8.7 µA were observed for the chloroform and DDT, respectively. Find the concentration of DDT in the unknown.
- Chloroform is an internal standard in the determination of the pesticide DDT in a polarographic analysis in which each compound is reduced at an electrode surface. A mixture containing 0.500 mM chloroform and 0.800 mM DDT gave signals of 15.3 µA for chloroform and 10.1 µA for DDT. An unknown solution (10.00 mL) containing DDT was placed in a 100-ml volumetric flask and 10.2 µl of chloroform (MW = 119.39, density = 1.484 g/mL) were added. After dilution to the mark with solvent, polarographic signals of 29.4 and 8.7 HA were observed for the chloroform and DDT, respectively. Find the concentration of DDT in the unknown. Dichlorodiphenyltrichloroethane (DDT) ÇI CI1 mL was taken from the sample filtrate and mixed with 13 mL pure water and 4 mL sulfomolybdic acid and 2 mL dilute SnCI2 solution by adding it, and after waiting for 15 minutes, the absorbance of the resulting solutions against pure water was read at 520 nm. if the function of the calibration graph obtained with standard phosphorus solutions of 0.5-2.5 mg/mL is y= 0.245x + 0.107 and the absorbance of the serum sample is 0.342, how many grams of phosphorus is the amount in the sample?What is the molar absorptivity coefficient? Question 13 options: 7.14 × 10–1 M–1 cm–1 1.40 × 103 M–1 cm–1 2.60 × 102 M–1 cm–1
- Find the standard deviation (if the mass of KHP in three experimental solutions are 0.467,0.48, and 0.48 and the volume of NaOH IN THE exp are 22,29,24 respectively in order to the masses of KHP ) the average molarity of NaOH in each experiment = 5.30x 10^-4 + 4.137x10^-4 + 5.0x10^-4 divided by 3 = 4.81x10^-4 ).(5) If 200 g of polymer A, 300 g of polymer B, 500 g polymer C, and 100 g of polymer D are mixed, calculate both M, and Mw of the blend? Polymer A Mn = 45,000; Polymer B M, = 100,000; Mw = 200,000 Polymer C M, = 80,000; Polymer D What are the polydispersity index and the standard deviation of the number distribution of molecular weight of the mixture? Mw = 65,000 Mw = 85,000 Mn = 300,000; Mw = 900,000To determine the molar concentration of a metal ion in a solution of unknown concentration, a student fırst made five standard solutions that contain the metal ion of interest and measured the absorbance of each solution in a spectrophotometer at its Amax- A calibration curve was obtained that had an equation of y = 5.747 x + 0.013 Next, the student pipetted 15.0 mL of the initial solution of unknown concentration into a 100.0 mL volumetric flask, and filled the flask with deionized water to the line. The absorbance of this final diluted solution was found to be A = 0.226 at Amax. The color of the original and diluted solution was blue. What is the molarity of the original solution, as well as an approximate Amax for this metal ion? 2max = 599 nm and concentration is 0.247 M Amax 457 nm and concentration is 0.247 M %3D 2 max = 457 nm and concentration is 0.0371 M 1 max 599 nm and concentration is 0.0371 M Amax = 599 nm and concentration is 0.00557 M
- A second spectrophotometric method for the quantitative analysis of Pb2+ in blood yields an Ssamp of 0.712 for a 5.00 mL sample of blood. After spiking the blood sample with 5.00 μL of a 1560 ppb Pb2+ external standard, an Sspike of 1.546 is measured. What is the concentration of Pb2+ in the original sample of blood?A controversy broke out as a dead body was found in a bar on Cornelia Street. The media revealed that minutes before the person died, he described his drink as something stronger than other drinks in the bar. You were the analyst tasked to verify the cause of death. Preliminary qualitative tests showed the possible presence of cyanide in the victim's death. Thus, you tried to quantitatively detect cyanide ions in the victim's drink using spectrophotometric analysis. Standard solutions were of different CN- concentrations were made as shown in Table 2. A 25.0mL aliquot of each standard solution was added with Fe(NO3)3 to form the colored complex, [Fe(CN)6]³ (aq). Each standard solution was then diluted to a total volume of 50.0 mL. The absorbances of the diluted standard solutions were recorded using 1.00-cm cells and at Amax = 725 nm and found in Table 2. Table 2. Raw absorbance measurements for each standard solution of CN-. [CN-] prior to dilution, M Abs@725nm 0.002 0.000 0.040 0.160…A 10.00 mL of natural water sample containing Ni2+ was pipetted into a volumetric flask and diluted to 50.00 mL with pure water. In the second 10.00 mL of natural water sample transferred into a volumetric flask, exactly 4.00 mL of a Ni2+ solution with a concentration of 5.99 mg/L was added and then diluted to 50.00 mL with pure water. The measured absorbance is A1= 0.436 and A2 = 0.663. What is the Ni2+ concentration in unit of mg/L in the natural water sample?