3. The following activation parameters have been measured (30 °C in MeOH) for the reaction k trans-[PtL2Cl2] + py [PtL2Clpy] + CI L AH* /kJ mol-1 AS/J K¹ mol-1 AV/cm³ mol-1 pyridine 49.3 -94 -8.8 PEt3 53.9 -100 -13.6 i. Explain briefly how the parameters are determined experimentally. ii. What mechanistic information can be obtained from the values? iii. Calculate the rate constant at 25.0 °C when L = = pyridine

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section11.3: Rate Law And Order Of Reactions
Problem 11.5PSP
icon
Related questions
Question
None
3.
The following activation parameters have been measured (30 °C in MeOH) for the
reaction
k
trans-[PtL2Cl2] + py
[PtL2Clpy] + CI
L
AH* /kJ mol-1
AS/J K¹ mol-1
AV/cm³ mol-1
pyridine
49.3
-94
-8.8
PEt3
53.9
-100
-13.6
i.
Explain briefly how the parameters are determined experimentally.
ii.
What mechanistic information can be obtained from the values?
iii. Calculate the rate constant at 25.0 °C when L =
= pyridine
Transcribed Image Text:3. The following activation parameters have been measured (30 °C in MeOH) for the reaction k trans-[PtL2Cl2] + py [PtL2Clpy] + CI L AH* /kJ mol-1 AS/J K¹ mol-1 AV/cm³ mol-1 pyridine 49.3 -94 -8.8 PEt3 53.9 -100 -13.6 i. Explain briefly how the parameters are determined experimentally. ii. What mechanistic information can be obtained from the values? iii. Calculate the rate constant at 25.0 °C when L = = pyridine
Expert Solution
steps

Step by step

Solved in 2 steps with 3 images

Blurred answer
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry: The Molecular Science
Chemistry: The Molecular Science
Chemistry
ISBN:
9781285199047
Author:
John W. Moore, Conrad L. Stanitski
Publisher:
Cengage Learning
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Fundamentals Of Analytical Chemistry
Fundamentals Of Analytical Chemistry
Chemistry
ISBN:
9781285640686
Author:
Skoog
Publisher:
Cengage
Appl Of Ms Excel In Analytical Chemistry
Appl Of Ms Excel In Analytical Chemistry
Chemistry
ISBN:
9781285686691
Author:
Crouch
Publisher:
Cengage
Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781337399074
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781133949640
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning