3. The following activation parameters have been measured (30 °C in MeOH) for the reaction k trans-[PtL2Cl2] + py [PtL2Clpy] + CI L AH* /kJ mol-1 AS/J K¹ mol-1 AV/cm³ mol-1 pyridine 49.3 -94 -8.8 PEt3 53.9 -100 -13.6 i. Explain briefly how the parameters are determined experimentally. ii. What mechanistic information can be obtained from the values? iii. Calculate the rate constant at 25.0 °C when L = = pyridine
3. The following activation parameters have been measured (30 °C in MeOH) for the reaction k trans-[PtL2Cl2] + py [PtL2Clpy] + CI L AH* /kJ mol-1 AS/J K¹ mol-1 AV/cm³ mol-1 pyridine 49.3 -94 -8.8 PEt3 53.9 -100 -13.6 i. Explain briefly how the parameters are determined experimentally. ii. What mechanistic information can be obtained from the values? iii. Calculate the rate constant at 25.0 °C when L = = pyridine
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section11.3: Rate Law And Order Of Reactions
Problem 11.5PSP
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