Determine by describing the structure of the products that will form when acid catalyzed water is removed from trans-2-methyl cyclohexane and sodium methoxide base and hydrogen bromide are removed from trans-1-bromo 4-methyl cyclohexane can you solve this question with mechanism ? keep question specific and include all details

Determine by describing the structure of the products that will form when acid catalyzed water is removed from trans-2-methyl cyclohexane and sodium methoxide base and hydrogen bromide are removed from trans-1-bromo 4-methyl cyclohexane can you solve this question with mechanism ? keep question specific and include all details

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter17: Alcohols And Phenols

Section17.SE: Something Extra

Problem 71AP: A problem often encountered in the oxidation of primary alcohols to acids is that esters are...

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Using the curved arrow convention, write a detailed, step-by-step mechanism for the reaction of 2-methyl-2-butanol with HCl to produce 2-chloro-2-methylbutane and water. Label the rate-determining step and state the reaction type. How would doubling the concentration of HCl affect the rate of this reaction in 1A? Write the rate equation for this reaction.
In the second paragraph you should explain why 2-chloro-2-methylpropane reacts with water via the SN1 mechanism instead of the SN2 mechanism, and then write the steps in the mechanism for this reaction. Then write the balanced equation for the reaction between 2-methyl-2-chloropropane and water. One of the products of this reaction is HCl. The rate at which HCl is produced is equal to the rate at which 2-chloro-2-methylpropane is consumed. In this experiment, the HCI will be neutralized by incremental addition of a sodium hydroxide solution. Write the balanced equation for the reaction between NaOH and HCI.
The rate of elimination of cis-1-bromo-4(1,1-dimethyl)cyclohexane is proportional to the concentration of both substrate and base, but that of the trans isomer is proportional only to the concentration of the substrate. a) draw the structures of cis and trans 1-bromo-4(1,1,-dimethyl)cyclohexane b) explain the difference in kinetics between the elimination reaction of cis and trans isomers.
Why is the product only methyl 3-nitrobenzoate? Hint: why does nitration occur in the meta position only?
This reaction does not follow the expected theory. Given what you know about substitution/elimination, what is the expected mechanism this reaction should follow? Suggest why that is not what happens and give the actual product of the reaction. Br ткон s
Alcohols are acidic in nature. Therefore, a strong base can abstract the acidic hydrogen atom of the alcohol in a process known as deprotonation. The alcohol forms an alkoxide ion by losing the proton attached to the oxygen atom of the hydroxyl ( -OH) group. The alkoxide formed can act as a base or a nucleophile depending on the substrate and reaction conditions. However, not all bases can abstract the acidic proton of alcohols and not all alcohols easily lose the proton. Deprotonation depends on the strength of the base and the acidity of the alcohol. Strong bases, such as NaNH2, can easily abstract a proton from almost all alcohols. Likewise, more acidic alcohols lose a proton more easily. Determine which of the following reactions would undergo deprotonation based on the strength of the base and the acidity of the alcohol. Check all that apply. ► View Available Hint(s) CH3CH,OH + NH3 →CH,CH,O-NH CH3 CH3 H3C-C-H+NH3 → H3 C-C-H OH O-NH CH3CH2OH + NaNH, → CH3CH,O-Na* + NH3 CHC12 Cl₂…
2) Organocuprates are important nucleophile in organic chemistry. They are usually generated from Grignard reagents (equation below). Draw a picture of the transition state for this reaction and why is the product formation favorable. CuR MgBrl Cul + +
The conversion of alcohols into alkyl halides by reaction with hydrogen halides is an example of a Nucleophilic Substitution Reaction. This kind of reaction can proceed by two different mechanisms depending on the structure of alcohol substrates used. Generally, primary alcohols are substituted via SN2 mechanism, while secondary and tertiary alcohols undergo SN1 mechanism. Consider the following reaction given in the picture below and the questions in the picture too.
If the following molecules undergo free radical substitution, what is the order in which the hydrogen is easily replaced by bromine?
The relative rates of reaction of ethane, toluene, and ethylbenzene with bromine atoms have been measured. The most reactive hydrocarbon undergoes hydrogen atom abstraction a million times faster than does the least reactive one. Arrange these hydrocarbons order of decreasing reactivity.
Fill the blank space. Compounds containing a phenol group may work as ANTIOXIDANTS to prevent free radical damage. This is accomplished when a free radical (or UV light) encounters a phenol group, turning the phenol group into a radical. However, contrary to typical radical behavior, the structure of the phenol radical can neutralize (or quench) the unpaired electron. Specifically, the phenol structure neutralizes (or quenches) the unpaired radical electron by doing the following: taking the electron and ---------. The correct name (or abbreviation) of an example compound containing a phenol group with antioxidant properties is: ---------.
1.The reduction of butanoic acid can form butanal and butan-1-ol. The boiling points of these compounds are shown in Table 1 below. Table 1-Boiling points of butanyl- compounds. Boiling Point (°C) Compound butan 1-ol 120 butanal 75 butanoic acid 164 a) Write a balanced chemical equation for this reaction.. Clearly indicate what conditions, catalysts, solvents, or other reagents would be required to perform this reaction. Include state symbols. b) Explain, with reference to intermolecular forces, how the process of distillation could be used to separate butan-1-ol from the other organic compounds in this reaction mixture. c) Describe an experimental procedure for a simple test that can be performed to confirm that the sample of butan-1-ol obtained by distillation does not contain any butanoic acid.